N-(p-Tolyl)-1-naphthylamine SAFETY DATA SHEET Section 1. IDENTIFICATION Product name: N-(p-Tolyl)-1-naphthylamine Section 2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDS Not classified HEALTH HAZARDS Skin corrosion/irritation Category 2
Category 2A Serious eye damage/eye irritation ENVIRONMENTAL HAZARDS Not classified GHS label elements, including precautionary statements Pictograms or hazard symbols Signal word Warning Hazard statements Causes skin irritation
Causes serious eye irritation Precautionary statements:
Wash hands thoroughly after handling. [Prevention]
Wear protective gloves/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, [Response]
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Gently wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash before reuse. Section 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture: Substance Components: N-(p-Tolyl)-1-naphthylamine Percent: >96.0%(GC) CAS Number: 634-43-5 Synonyms: 1-(p-Toluidino)naphthalene
C17H15N Chemical Formula: Section 4. FIRST AID MEASURES Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention if you feel unwell. N-(p-Tolyl)-1-naphthylamine Section 4. FIRST AID MEASURES Skin contact: Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
soap and water. If skin irritation or rash occurs: Get medical advice/attention. Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention. Ingestion: Get medical advice/attention if you feel unwell. Rinse mouth.
A rescuer should wear personal protective equipment, such as rubber gloves and air- Protection of first-aiders:
tight goggles. Section 5. FIRE-FIGHTING MEASURES Suitable extinguishing Dry chemical, foam, water spray, carbon dioxide. media: Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to from the chemical: generate poisonous fume. Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so. Special protective When extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section 6. ACCIDENTAL RELEASE MEASURES Personal precautions, Use personal protective equipment. Keep people away from and upwind of spill/leak. protective equipment and Entry to non-involved personnel should be controlled around the leakage area by emergency procedures: roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it. containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with up: appropriate laws and regulations. Section 7. HANDLING AND STORAGE Precautions for safe handling Technical measures: Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent dispersion of dust. Wash hands and face thoroughly after handling.
Use a local exhaust if dust or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Storage conditions: Keep container tightly closed. Store in a cool and dark place.
Store under inert gas.
Store away from incompatible materials such as oxidizing agents.
Air-sensitive Packaging material: Comply with laws. Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: Install a closed system or local exhaust as possible so that workers should not be
exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Dust respirator. Follow local and national regulations. Hand protection: Protective gloves.
Safety glasses. A face-shield, if the situation requires. Eye protection: Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C): Solid
Crystal- Powder Form: N-(p-Tolyl)-1-naphthylamine Section 9. PHYSICAL AND CHEMICAL PROPERTIES Colour: Pale yellow - Greyish yellow red Odour: No data available pH: No data available Melting point/freezing point:78°C Boiling point/range: 360°C/70kPa Flash point: No data available Flammability or explosive limits: Lower: No data available Upper: No data available Relative density: No data available Solubility(ies): [Water] No data available [Other solvents] Soluble: Methanol Section 10. STABILITY AND REACTIVITY Chemical stability: Stable under proper conditions. Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx) products: Section 11. TOXICOLOGICAL INFORMATION Acute Toxicity: No data available Skin corrosion/irritation: No data available Serious eye No data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC = No data available NTP = No data available Reproductive toxicity: No data available Section 12. ECOLOGICAL INFORMATION Ecotoxicity:
No data available Fish: Crustacea: No data available
No data available Algae: Persistence / degradability: No data available
No data available Bioaccumulative potential(BCF): Mobility in soil Log Pow: No data available
No data available Soil adsorption (Koc): Henry's Law No data available constant(PaM3/mol): Section 13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
Observe all federal, state and local regulations when disposing of the substance. Section 14. TRANSPORT INFORMATION Hazards Class: Does not correspond to the classification standard of the United Nations N-(p-Tolyl)-1-naphthylamine Section 14. TRANSPORT INFORMATION UN-No: Not listed Section 15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.