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SECTION 1: Identification of the substance/mixture and of the company/undertaking
  Product identifiers
    Product name        : Bromomethane-d2    
    REACH No.        : A registration number is not available for this substance as the substance    
    or its uses are exempted from registration, the annual tonnage does not
    require a registration or the registration is envisaged for a later
    registration deadline.
    CAS-No.        : 4960-89-8    
  Relevant identified uses of the substance or mixture and uses advised against
    Identified uses        : Laboratory chemicals, Manufacture of substances    
  
  

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SECTION 2: Hazards identification
  Classification of the substance or mixture
  Classification according to Regulation (EC) No 1272/2008
    Gases under pressure
    Germ cell mutagenicity (Category 2), H341
    Acute toxicity, Inhalation (Category 3), H331
    Acute toxicity, Oral (Category 3), H301
    Specific target organ toxicity - repeated exposure (Category 2), H373
    Eye irritation (Category 2), H319
    Specific target organ toxicity - single exposure (Category 3), H335
    Skin irritation (Category 2), H315
    Acute aquatic toxicity (Category 1), H400
    Hazardous to the ozone layer, EUH059
    For the full text of the H-Statements mentioned in this Section, see Section 16.
  Classification according to EU Directives 67/548/EEC or 1999/45/EC
    R68
    N Dangerous for the        R50    
    environment
    R59
    T Toxic        R23/25    
    Xi Irritant        R36/37/38    
    Xn Harmful        R48/20    
    N Dangerous for the
    environment
    For the full text of the R-phrases mentioned in this Section, see Section 16.
  Label elements
  Labelling according Regulation (EC) No 1272/2008
    Pictogram
    Signal word        Danger    
    Hazard statement(s)
    H301        Toxic if swallowed.    
    H315        Causes skin irritation.    
    H319        Causes serious eye irritation.    
    H331        Toxic if inhaled.    
    H335        May cause respiratory irritation.    
    H341        Suspected of causing genetic defects.    
    H373        May cause damage to organs through prolonged or repeated exposure.    
    H400        Very toxic to aquatic life.    
    Precautionary statement(s)
    P261        Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.    
    P273        Avoid release to the environment.    
    P281        Use personal protective equipment as required.    
    P301 + P310        IF SWALLOWED: Immediately call a POISON CENTER or doctor/    
    physician.
    P305 + P351 + P338        IF IN EYES: Rinse cautiously with water for several minutes. Remove    
    contact lenses, if present and easy to do. Continue rinsing.
    P311        Call a POISON CENTER or doctor/ physician.    
    Supplemental Hazard information (EU)
    EUH059        Hazardous to the ozone layer.    
  Other hazards - none

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SECTION 3: Composition/information on ingredients
  Substances
    Chemical characterization : Isotopically labeled
    Formula        : CD2HBr    
    Molecular Weight        : 96,95 g/mol    
    CAS-No.        : 4960-89-8    
  Hazardous ingredients according to Regulation (EC) No 1272/2008
    Component        Classification        Concentration    
  Bromomethane-d2
    Press. Gas ; Muta. 2; Acute        -    
    Tox. 3; STOT RE 2; Eye Irrit.
    2; STOT SE 3; Skin Irrit. 2;
    Aquatic Acute 1; Ozone ;
    H301, H315, H319, H331,
    H335, H341, H373, H400,
    EUH059
  Hazardous ingredients according to Directive 1999/45/EC
    Component        Classification        Concentration    
  Bromomethane-d2
    T, N, Mut.Cat.3, R23/25 -        -    
    R36/37/38 - R48/20 - R50 -
    R59 - R68
    For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

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SECTION 4: First aid measures
  Description of first aid measures
  General advice
    Consult a physician. Show this safety data sheet to the doctor in attendance.
  If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
  In case of skin contact
    Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
  In case of eye contact
    Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
  If swallowed
    Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
    water. Consult a physician.
  Most important symptoms and effects, both acute and delayed
    The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
    section 11
  Indication of any immediate medical attention and special treatment needed
    no data available

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SECTION 5: Firefighting measures
  Extinguishing media
  Suitable extinguishing media
    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
  Special hazards arising from the substance or mixture
    Carbon oxides, Hydrogen bromide gas
  Advice for firefighters
    Wear self contained breathing apparatus for fire fighting if necessary.
  Further information
    Use water spray to cool unopened containers.

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SECTION 6: Accidental release measures
  Personal precautions, protective equipment and emergency procedures
    Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove
    all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form
    explosive concentrations. Vapours can accumulate in low areas.
    For personal protection see section 8.
  Environmental precautions
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
    environment must be avoided.
  Methods and materials for containment and cleaning up
    Clean up promptly by sweeping or vacuum.
  Reference to other sections
    For disposal see section 13.

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SECTION 7: Handling and storage
  Precautions for safe handling
    Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
    Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
    charge.
    For precautions see section 2.2.
  Conditions for safe storage, including any incompatibilities
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
    Store under inert gas. hygroscopic
  Specific end use(s)
    A part from the uses mentioned in section 1.2 no other specific uses are stipulated

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SECTION 8: Exposure controls/personal protection
  Control parameters
  Components with workplace control parameters
  Exposure controls
  Appropriate engineering controls
    Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
    the product.
  Personal protective equipment
  Eye/face protection
    Face shield and safety glasses Use equipment for eye protection tested and approved under
    appropriate government standards such as NIOSH (US) or EN 166(EU).
  Skin protection
    Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
    (without touching glove's outer surface) to avoid skin contact with this product. Dispose of
    contaminated gloves after use in accordance with applicable laws and good laboratory practices.
    Wash and dry hands.
    The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
    the standard EN 374 derived from it.
  Body Protection
    Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type
    of protective equipment must be selected according to the concentration and amount of the
    dangerous substance at the specific workplace.
  Respiratory protection
    Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
    with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup
    to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
    respirator. Use respirators and components tested and approved under appropriate government
    standards such as NIOSH (US) or CEN (EU).
  Control of environmental exposure
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
    the environment must be avoided.

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SECTION 9: Physical and chemical properties
  Information on basic physical and chemical properties
    a) Appearance        Form: gaseous    
    Colour: colourlesscolourless
    b) Odour        no data available    
    c) Odour Threshold        no data available    
    d) pH        no data available    
    e) Melting point/freezing        Melting point/range: -94 °C    
    point
    f) Initial boiling point and 4 °C - lit.
    boiling range
    g) Flash point        no data available    
    h) Evapouration rate        no data available    
    i) Flammability (solid, gas) no data available
    j) Upper/lower        Upper explosion limit: 20 %(V) at 1013 hPa    
    flammability or        Lower explosion limit: 8,6 %(V) at 1013 hPa    
    explosive limits
    k) Vapour pressure        no data available    
    l) Vapour density        no data available    
    m) Relative density        no data available    
    n) Water solubility        no data available    
    o) Partition coefficient: n- no data available
    octanol/water
    p) Auto-ignition        no data available    
    temperature
    q) Decomposition        no data available    
    temperature
    r) Viscosity        no data available    
    s) Explosive properties        no data available    
    t) Oxidizing properties        no data available    
  Other safety information
    no data available

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SECTION 10: Stability and reactivity
  Reactivity
    no data available
  Chemical stability
    Stable
    Stable under recommended storage conditions.
  Possibility of hazardous reactions
    no data available
  Conditions to avoid
    Heat, flames and sparks. Extremes of temperature and direct sunlight.
  Incompatible materials
    Oxidizing agents
  Hazardous decomposition products
    Other decomposition products - no data available
    In the event of fire: see section 5

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SECTION 11: Toxicological information
  Information on toxicological effects
  Acute toxicity
    no data available
  Skin corrosion/irritation
    no data available
  Serious eye damage/eye irritation
  Respiratory or skin sensitisation
    no data available
  Germ cell mutagenicity
    In vitro tests showed mutagenic effects
  Carcinogenicity
    IARC:        3 - Group 3: Not classifiable as to its carcinogenicity to humans (Bromomethane-d2)    
  Reproductive toxicity
  Specific target organ toxicity - single exposure
    May cause respiratory irritation.
  Specific target organ toxicity - repeated exposure
    no data available
  Aspiration hazard
    no data available
  Additional Information
    RTECS: Not available
    Repeated splashes on the skin results in severe skin lesions, with severe cases showing vesicles or blebs.
    In lesser exposure cases a severe itching dermatitis can develop. Overexposure to bromomethane may
    cause headache, dizziness, nausea, vomiting, blurred vision, slurred speech, and convulsions in the short-
    term. Prolonged or repeated exposure may cause a variety of symptoms and signs mostly due to injury of
    the central nervous system. These include visual disturbances, slurred speech, numbness and tingling of
    the arms and legs, confusion, shaking, and unconsciousness. The symptoms may stop within a few days
    after the termination of exposure or may last for several months. Usually recovery is complete., Damage to
    the eyes., Liver injury may occur., Kidney injury may occur., Damage to the lungs., Material is extremely
    destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm,
    inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis,
    pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache,
    Nausea, Vomiting

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SECTION 12: Ecological information
  Toxicity
    no data available
  Persistence and degradability
    no data available
  Bioaccumulative potential
    no data available
  Mobility in soil
    no data available
  Results of PBT and vPvB assessment
    PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
  Other adverse effects
    Very toxic to aquatic life.

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SECTION 13: Disposal considerations
  Waste treatment methods
  Product
    Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
    as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
    company.
  Contaminated packaging
    Dispose of as unused product.

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SECTION 14: Transport information
  UN number
    ADR/RID: 1062        IMDG: 1062        IATA: 1062    
  UN proper shipping name
    ADR/RID: METHYL BROMIDE
    IMDG: METHYL BROMIDE
    IATA:        Methyl bromide    
    Passenger Aircraft: Not permitted for transport
    Cargo Aircraft: Not permitted for transport
  Transport hazard class(es)
    ADR/RID: 2.3        IMDG: 2.3        IATA: 2.3    
  Packaging group
    ADR/RID: -        IMDG: -        IATA: -    
  Environmental hazards
    ADR/RID: yes        IMDG Marine pollutant: yes        IATA: no    
  Special precautions for user
    no data available

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SECTION 15 - REGULATORY INFORMATION
N/A

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SECTION 16 - ADDITIONAL INFORMATION
N/A