Name:	Acetic-D3 Acid-D Packaged in 1ml Ampules 99.5 Atom% D Material Safety Data Sheet
Synonym:	Ethanoic acid; Ethylic acid; Glacial acetic acid; Methanecarboxylic acid; Pyroligeneous acid; Vinegar aci
CAS:	1186-52-3

Section 1 - Chemical Product   MSDS Name:Acetic-D3 Acid-D Packaged in 1ml Ampules 99.5 Atom% D Material Safety Data Sheet
Synonym:Ethanoic acid; Ethylic acid; Glacial acetic acid; Methanecarboxylic acid; Pyroligeneous acid; Vinegar aci

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
1186-52-3	Acetic-D3 Acid-D	99.5	214-693-4

Hazard Symbols: C
Risk Phrases: 10 35

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Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Causes severe burns.Hygroscopic (absorbs moisture from the air).Corrosive.Lachrymator (substance which increases the flow of tears).
Potential Health Effects
Eye:
Contact with liquid or vapor causes severe burns and possible irreversible eye damage. Lachrymator (substance which increases the flow of tears).
Skin:
Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
May be harmful if absorbed through the skin. Contact with the skin may cause blackening and hyperkeratosis of the skin of the hands.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. Causes severe pain, nausea, vomiting, diarrhea, and shock. May cause polyuria, oliguria (excretion of a diminished amount of urine in relation to the fluid intake) and anuria (complete suppression of urination). Rapidly absorbed from the gastrointestinal tract.
Inhalation:
Effects may be delayed. Causes chemical burns to the respiratory tract. Exposure may lead to bronchitis, pharyngitis, and dental erosion. May be absorbed through the lungs.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth. May cause reproductive and fetal effects.
Laboratory experiments have resulted in mutagenic effects. Repeated exposure may lead to blackening and hyperkeratosis of the skin and hands, conjunctivitis, bronchitis and pharyngitis and erosion of the teeth. Prolonged exposure may cause corneal erosion, conjunctivitis, and possible blindness.

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Section 4 - FIRST AID MEASURES
  Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Persons with pre-existing skin disorders or impaired respiratory or pulmonary function may be at increased risk to the effects of this substance. Treat symptomatically and supportively.
Antidote: No specific antidote exists.

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Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Reacts with most metals to form highly flammable hydrogen gas which can form explosive mixtures with air. Flammable liquid and vapor. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined areas. May be ignited by friction, heat, sparks, or flame. May polymerize explosively when involved in a fire. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Do NOT get water inside containers. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water.

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Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Wash area with soap and water. Use water spray to disperse the gas/vapor. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Cover with material such as dry soda ash or calcium carbonate and place into a closed container for disposal. A vapor suppressing foam may be used to reduce vapors.

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Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale. Use only in a chemical fume hood. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep under a nitrogen blanket. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.
Corrosives area. Store in a suitable container in a dry area above the substance's freezing point. Do not store near alkaline substances.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 1186-52-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: pungent odor - vinegar odor
pH: 2.4 (1M), 2.9 (0.1M)
Vapor Pressure: 11.4 mm Hg
Viscosity: 1.22 cP
Boiling Point: 117-118 deg C
Freezing/Melting Point: 16.6 deg C
Autoignition Temperature: 426 deg C ( 798.80 deg F)
Flash Point: 39 deg C ( 102.20 deg F)
Explosion Limits, lower: 4.0 vol %
Explosion Limits, upper: 19.9 vol %
Decomposition Temperature: Not available.
Solubility in water: Soluble in water; releases heat/vapor.
Specific Gravity/Density: 1.05 (Water=1)
Molecular Formula: C2D4O2
Molecular Weight: 64.0548

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Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Metals, acetic anhydride, alcohols, amines, ammonium nitrate, chlorine trifluoride, nitric acid, permanganates, peroxides, sodium hydroxide, sodium peroxide, hydrogen peroxides, acetaldehyde, caustics (e.g. ammonia, ammonium hydroxide, calcium hydroxide, potassium hydroxide, sodium hydroxide), acid anhydrides, chlorosulfonic acid, oleum, chromium trioxide, potassium hydroxide, carbonates, bromine pentafluoride, perchloric acid, chromic anhydride, potassium-tert-butoxide, calcium salts, ethyleneimine, Attacks some forms of plastics, rubbers, and coatings., 2-aminoethanol, ethylene diamine, phosphorus trichloride, chromic acid anhydride, phosphorus isocyanate, diallyl methyl carbinol + ozone, nitric acid + acetone, xylene, sodium salts.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: May occur.

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Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 1186-52-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Acetic-D3 Acid-D - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Fathead Minnow: LC50 = 88 mg/L; 96 Hr; Static bioassay @ 18-22CFish: Bluegill/Sunfish: LC50 = 75 mg/L; 96 Hr; UnspecifiedFish: Goldfish: LC50 = 423 mg/L; 24 Hr; UnspecifiedWater flea Daphnia: EC50 = 32-47 mg/L; 24-48 Hr; UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 = 8.86-11 mg/L; 5,15,25 min; Microtox testIf released to water or soil, acetic acid will biodegrade readily. Evaporation from dry surfaces is likely to occur. When spilled on soil, the liquid will spread on the surface and penetrate into the soil at a rate dependent on the soil type and its water content. Acetic acid shows no potential for biological

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Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

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Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 35 Causes severe burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1186-52-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1186-52-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1186-52-3 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A