Diethanolamine

CAS No. 111-42-2

Formula: C4H11NO2
Basic Info

Diethanolamine, often abbreviated as DEA or DEOA, is an organic compound with the formula HN(CH2CH2OH)2. Pure diethanolamine is a white solid at room temperature, but its tendency to absorb water and to supercool mean it is often encountered as a colorless, viscous liquid. Diethanolamine is polyfunctional, being a secondary amine and a diol. Like other organic amines, diethanolamine acts as a weak base. Reflecting the hydrophilic character of the secondary amine and hydroxyl groups, DEA is soluble in water. Amides prepared from DEA are often also hydrophilic.

Formula
C4H11NO2
Molecular Weight
105.136
Exact Mass
105.079
LogP
-1.0485
PSA
52.49
Synonyms

DEA

2,2'-Iminodiethanol

Ethanol, 2,2‘-iminobis-

2,2'-Azanediyldiethanol

bis-(2-hydroxy-ethyl)-amine

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Properties
Appearance & Physical State
solid or viscous liquid with an amine odour
Density
1.096
Boiling Point
268ºC
Melting Point
27-30ºC
Flash Point
179ºC
Refractive Index
1.475-1.479
Water Solubility
MISCIBLE
Stability
Stable. Incompatible with carbon dioxide, strong acids, strong oxidizing agents. Deliquescent.
Storage Condition
Store at RT
Vapor Density
3.6 (vs air)
Vapor Pressure
<0.98 atm ( 100 °C)
Safety Info
RTECS
KL2975000
Safety Statements
S26-S36/37/39-S46
WGK Germany
1
Risk Statements
R22; R38; R41; R48/22
HS Code
2922120090
RIDADR
UN 1760
Packing Group
II
Caution Statement
P273; P280; P301 + P312 + P330; P305 + P351 + P338 + P310
Hazard Codes
MSDS
SDS 1.0
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SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Diethanolamine

1.2 Other means of identification

Product number -
Other names DEA

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Diethanolamine is used in cutting oils, soaps, shampoos, cleaners, polishers, cosmetics, and pharmaceuticals. It is also used as an intermediate in the rubber chemicals industry, as a humectant and softening agent, and as an emulsifier and dispersing agent in various agricultural chemicals.
Uses advised against no data available

1.4 Supplier's details

Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
Xuhui District, Shanghai, China
Telephone +86(21)64956998
Fax +86(21)54365166

1.5 Emergency phone number

Emergency phone number +86-400-6021-666
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Acute toxicity - Oral, Category 4

Skin irritation, Category 2

Serious eye damage, Category 1

Specific target organ toxicity – repeated exposure, Category 2

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Danger

Hazard statement(s)

H302 Harmful if swallowed

H315 Causes skin irritation

H318 Causes serious eye damage

Precautionary statement(s)
Prevention

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

Response

P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/…if you feel unwell.

P330 Rinse mouth.

P302+P352 IF ON SKIN: Wash with plenty of water/...

P321 Specific treatment (see ... on this label).

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER/doctor/…

P314 Get medical advice/attention if you feel unwell.

Storage

none

Disposal

P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
Diethanolamine Diethanolamine 111-42-2 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

Fresh air, rest.

In case of skin contact

Remove contaminated clothes. Rinse skin with plenty of water or shower.

In case of eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

If swallowed

Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention . Rest.

4.2 Most important symptoms/effects, acute and delayed

Irritation of eyes and skin. Breathing vapors may cause coughing, a smothering sensation, nausea, headache. (USCG, 1999)

4.3 Indication of immediate medical attention and special treatment needed, if necessary

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Organic bases/Amines and related compounds/

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Wear self contained breathing apparatus for fire fighting if necessary.

5.2 Specific hazards arising from the chemical

Special Hazards of Combustion Products: Irritating vapors are generated when heated. (USCG, 1999)

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Personal protection: filter respirator for organic gases and particulates adapted to the airborne concentration of the substance. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Then store and dispose of according to local regulations.

6.3 Methods and materials for containment and cleaning up

Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Separated from strong oxidants and acids. Dry.Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Air sensitive.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

Recommended Exposure Limit: 10 Hour Time-Weighted Average: 3 ppm (15 mg/cu m).

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state solid or viscous liquid with an amine odour
Colour A faintly colored, viscous liquid or deliquescent prisms
Odour Mild, ammonia-like odor
Melting point/ freezing point 255°C(lit.)
Boiling point or initial boiling point and boiling range 217°C/150mmHg(lit.)
Flammability Class IIIB Combustible Liquid: Fl.P. at or above 93.33°C.Combustible SolidCombustible.
Lower and upper explosion limit / flammability limit Lower flammable limit: 1.6% by volume (calculated); Upper flammable limit: 9.8% by volume (estimated)
Flash point 138°C
Auto-ignition temperature 365°C
Decomposition temperature no data available
pH Strong base. pH of 0.1 N aqueous solution: 11.0
Kinematic viscosity 351.9 cP at 30°C; 53.85 cP at 60°C
Solubility In water:MISCIBLE
Partition coefficient n-octanol/water (log value) log Kow= - 1.43
Vapour pressure <0.98 atm ( 100 °C)
Density and/or relative density 1.097g/mLat 25°C(lit.)
Relative vapour density 3.6 (vs air)
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Combustile, when exposed to heat or flame; can react with oxidizing materials.The vapour is heavier than air.DIETHANOLAMINE is an aminoalcohol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. This compound is hygroscopic. It may be sensitive to exposure to air and light. This compound can react with oxidizing materials, acids, CO2, copper alloys, aluminum, zinc, galvanized iron and copper.

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

DEA (Diethanolamine) degrades in the presense of carbon dioxide to yield HEOD [3-(2-hydroxy-ethyl)oxazolidone], THEED [N,N,N,'-(2-hydroxyethyl)ethyleen-diamine] and BHEP [N,N'-bis(2-hydroxyethyl)piperazine.

10.6 Hazardous decomposition products

Special hazards arising from the substance or mixture: Carbon oxides, nitrogen oxides (NOx). Nature of decomposition products not known.

11.Toxicological information

Acute toxicity

  • Oral: LD50 Rat oral 710 mg/kg
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

Evaluation: Cancer in humans: There is inadequate evidence in humans for the carcinogenicity of diethanolamine. Cancer in experimental animals: There is sufficient evidence in experimental animals for the carcinogenicity of diethanolamine. Overall evaluation: Diethanolamine is possibly carcinogen to humans (Group 2B).

Reproductive toxicity

No information is available on the reproductive or developmental effects of diethanolamine in humans. Animal studies have reported testicular degeneration and reduced sperm motility and count from oral exposure to diethanolamine. (10)

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: LC50; Species: Lepomis macrochirus (Bluegill) weight 5 g, length 7 (5-11) cm; Conditions: freshwater, static, 20°C, pH 6.9-7.5, hardness 84.0-163 mg/L CaCO3, alkalinity 33.0-81.0 mg/L CaCO3, dissolved oxygen >5 mg/L; Concentration: 2100000 ug/L for 24 hr /formulation
  • Toxicity to daphnia and other aquatic invertebrates: LC50; Species: Daphnia magna (Water Flea) age < or =24 hr; Conditions: freshwater, static, 20-22°C, pH 7.6-7.7; Concentration: 180000 ug/L for 24 hr /formulation
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

AEROBIC: Biodegradation of diethanolamine has been reported in many die-away tests(1-3). N-Nitrosodiethanolamine has been identified as a metabolite of diethanolamine in natural water samples and sewage(2).Media Initial Concn Incubation Time (days) % Biodegradation Reference River Water 21 mg/L 4 5 1 River Water 210 ug/L 4 55 1 River Water 21 ng/L 4 32 1 Lake Water 1.1 ppm 14 31 2 Acidic Lake Water 1.1 ppm 14 1.2 2 Sewage 1.1 ppm 14 53 2 River Water 50 ppm 10 90 3

12.3 Bioaccumulative potential

An estimated BCF of 3 was calculated in fish for diethanolamine(SRC), using a log Kow of -1.43(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

12.4 Mobility in soil

The Koc of diethanolamine has been reported as 3.97(1) and an experimental log Koc of 0.60(2). According to a classification scheme(3), these Koc values suggest that diethanolamine is expected to have very high mobility in soil. The pKa of diethanolamine is 8.96(4), indicating that this compound will exist partially in cation form in the environment and cations generally adsorb more strongly to soils containing organic carbon and clay than their neutral counterparts(5). Diethanolamine has been shown to adsorb to humic acid which may be contained in soils and sediments(6). The adsorption of diethanolamine on humic acid changed very slightly from pH 4-8, (40-45% adsorption)(6).

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN3077 IMDG: UN3077 IATA: UN3077

14.2 UN Proper Shipping Name

ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
IATA: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

14.3 Transport hazard class(es)

ADR/RID: 9 IMDG: 9 IATA: 9

14.4 Packing group, if applicable

ADR/RID: II IMDG: II IATA: II

14.5 Environmental hazards

ADR/RID: no IMDG: no IATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
Diethanolamine Diethanolamine 111-42-2 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
EC Inventory Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
Vietnam National Chemical Inventory Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 10, 2017
Revision Date Aug 10, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
MSDS
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Name: Diethanolamine Solution 85.0% Material Safety Data Sheet
Synonym: Bis(2-hydroxyethyl)amine; DEA; Diethylolamine; 2,2'-Dihydroxydiethylamine; 2,2'-Iminodiethanol
CAS: 111-42-2
Section 1 - Chemical Product   MSDS Name:Diethanolamine Solution 85.0% Material Safety Data Sheet
Synonym:Bis(2-hydroxyethyl)amine; DEA; Diethylolamine; 2,2'-Dihydroxydiethylamine; 2,2'-Iminodiethanol

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
111-42-2 Diethanolamine 85.0 203-868-0
Hazard Symbols: XN
Risk Phrases: 22 38 41 48/22

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to skin. Risk of serious damage to eyes. Harmful : danger of serious damage to health by prolonged exposure if swallowed.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes severe eye irritation. May cause inflammation of the cornea and iris.
Skin:
May cause skin irritation. May be absorbed through the skin.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May cause lung damage.
Chronic:
May cause liver and kidney damage. May cause reproductive and fetal effects.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use carbon dioxide or dry chemical. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Storage under a nitrogen blanket has been recommended.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 111-42-2: Belgium - TWA: 0.46 ppm VLE; 2 mg/m3 VLE France - VME: 3 ppm VME; 15 mg/m3 VME Germany: 15 mg/m3 TWA (inhalable fraction) Germany: Skin absorber Malaysia: 0.46 ppm TWA; 2 mg/m3 TWA Netherlands: 0.46 ppm MAC; 2 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 0.46 ppm VLA-ED; 2 mg/m3 VLA-ED CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: Mild ammoniacal odor.
pH: Not available.
Vapor Pressure: < 0.01 mm Hg @ 20 deg C
Viscosity: 352 cps 30 deg C
Boiling Point: 268 deg C
Freezing/Melting Point: -6 deg C
Autoignition Temperature: 662 deg C ( 1,223.60 deg F)
Flash Point: 138 deg C ( 280.40 deg F)
Explosion Limits, lower: 1.6
Explosion Limits, upper: 9.8
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 1.09
Molecular Formula: C4H11NO2
Molecular Weight: 105.14

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Reacts with carbon dioxide from the air and formaldehyde.
Incompatibile with strong oxidizers, strong acids, acid anhydrides, and halides. Corrosive to copper, copper alloys, zinc, and galvanized iron. Heating of ethanolamines above 60C will cause darkening of material.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 111-42-2: KL2975000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 111-42-2: Dermal, guinea pig: LD50 = 11900 uL/kg; Draize test, rabbit, eye: 5500 mg Severe; Draize test, rabbit, eye: 750 ug/24H Severe; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, mouse: LD50 = 3300 mg/kg; Oral, rabbit: LD50 = 2200 mg/kg; Oral, rat: LD50 = 620 uL/kg; Skin, rabbit: LD50 = 7640 uL/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Diethanolamine - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Bluegill/Sunfish: 1800mg/L; 24HFish: Goldfish: 800mg/L; 24HFish: Fathead Minnow: LC50 = >100.00 mg/L; 96 Hr.; Static ConditionBacteria: Phytobacterium phosphoreum: EC50 = 5000 mg/L; 5 minutes; Microtox test Other For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND EXPOSURE DATA."

Section 13 - DISPOSAL CONSIDERATIONS
  Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 111-42-2: 100 lb final RQ; 45.4 kg final RQ

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
R 48/22 Harmful : danger of serious damage to health
by prolonged exposure if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 46 If swallowed, seek medical advice immediately
and show this container or label.
WGK (Water Danger/Protection)
CAS# 111-42-2: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 111-42-2 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 111-42-2 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-42-2 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Spectrum
NMR Spectrum 1H NMR : 90 MHz in CDCl3
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IR Spectrum IR : liquid film
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Mass Spectrum Mass
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Raman Spectrum Raman : 4880 A,200 M,liquid
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Analysis Methods
Kovats' RI, polar column, isothermal
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Column Shape
Packed
Active Phase(℃)
PEG-2000
Retention index
2200.
Temperature Control
179.
Method
isothermal
Comments
He, Celite 545 (44-60 mesh); Column length: 3. m
Reference
Anderson, A.Jurel, S.Shymanska, M.Golender, L.Gas-liquid chromatography of some aliphatic and heterocyclic mono- and pollyfunctional amines. VII. Retention indices of amines in some polar and unpolar stationary phasesLatv. PSR Zinat. Akad. Vestis Kim. Ser.1973, 1, 51-63.
Kovats' RI, polar column, isothermal
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Column Shape
Packed
Active Phase(℃)
PEG-2000
Retention index
2141.
Temperature Control
200.
Method
isothermal
Comments
He, Celite 545 (44-60 mesh); Column length: 3. m
Reference
Anderson, A.Jurel, S.Shymanska, M.Golender, L.Gas-liquid chromatography of some aliphatic and heterocyclic mono- and pollyfunctional amines. VII. Retention indices of amines in some polar and unpolar stationary phasesLatv. PSR Zinat. Akad. Vestis Kim. Ser.1973, 1, 51-63.
Kovats' RI, polar column, isothermal
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Column Shape
Packed
Active Phase(℃)
PEG-2000
Retention index
2180.
Temperature Control
200.
Method
isothermal
Comments
He, Celite 545 (44-60 mesh); Column length: 3. m
Reference
Anderson, A.Jurel, S.Shymanska, M.Golender, L.Gas-liquid chromatography of some aliphatic and heterocyclic mono- and pollyfunctional amines. VII. Retention indices of amines in some polar and unpolar stationary phasesLatv. PSR Zinat. Akad. Vestis Kim. Ser.1973, 1, 51-63.
Toxicity
OTHER MULTIPLE DOSE TOXICITY DATA
expand collapse
Type of Test
TDLo - Lowest published toxic dose
Exposure Route
Oral
Species Observed
Rodent - rat
Dose/Duration
52 gm/kg/14D-C
Toxic Effects
Kidney, Ureter, Bladder--other changes in urine composition<br>Blood--normocytic anemia<br>Biochemical-Enzyme inhibition, induction, or change in blood or tissue levels-dehydrogenases
Reference
National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NIH-92-3343
OTHER MULTIPLE DOSE TOXICITY DATA
expand collapse
Type of Test
TDLo - Lowest published toxic dose
Exposure Route
Oral
Species Observed
Rodent - rat
Dose/Duration
8827 mg/kg/13W-C
Toxic Effects
Kidney, Ureter, Bladder--changes in bladder weight<br>Blood--normocytic anemia<br>Related to Chronic Data--changes in testicular weight
Reference
National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NIH-92-3343
OTHER MULTIPLE DOSE TOXICITY DATA
expand collapse
Type of Test
TDLo - Lowest published toxic dose
Exposure Route
Oral
Species Observed
Rodent - rat
Dose/Duration
49 gm/kg/7W-C
Toxic Effects
Liver--other changes<br>Blood--normocytic anemia<br>Related to Chronic Data--death
Reference
Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 17,308,1970

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