Triethanolamine

CAS No. 102-71-6

Formula: C6H15NO3
Basic Info

Triethanolamine, often abbreviated as TEA, is a viscous organic compound that is both a tertiary amine and a triol. A triol is a molecule with three alcohol groups. Triethanolamine is a strong base. Triethanolamine can also be abbreviated as TEOA, which can help to distinguish it from triethylamine. Approximately 150,000 metric tons were produced in 1999. It is a colourless compound although samples may appear yellow because of impurities.

Formula
C6H15NO3
Molecular Weight
149.188
Exact Mass
149.105
LogP
-1.7347
PSA
63.93
Synonyms

2,2',2''-Nitrilotriethanol

Ethanol, 2,2‘,2‘‘-nitrilotris-

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Properties
Appearance & Physical State
Colorless to light yellow, viscous liquid
Density
1.1245
Boiling Point
360ºC
Melting Point
21ºC
Flash Point
190ºC
Refractive Index
1.484-1.486
Water Solubility
soluble
Storage Condition
Store at RT.
Vapor Density
5.14 (vs air)
Vapor Pressure
0.01 mm Hg ( 20 °C)
Safety Info
RTECS
KL9275000
Safety Statements
S26-S39
WGK Germany
1
Risk Statements
R36
HS Code
2922131000
Hazard Codes
MSDS
SDS 1.0
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SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name Triethanolamine

1.2 Other means of identification

Product number -
Other names 2,2',2''-Nitrilotriethanol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Specialized Industrial Chemicals
Uses advised against no data available

1.4 Supplier's details

Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
Xuhui District, Shanghai, China
Telephone +86(21)64956998
Fax +86(21)54365166

1.5 Emergency phone number

Emergency phone number +86-400-6021-666
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Not classified.

2.2 GHS label elements, including precautionary statements

Pictogram(s) No symbol.
Signal word

No signal word.

Hazard statement(s)

none

Precautionary statement(s)
Prevention

none

Response

none

Storage

none

Disposal

none

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
Triethanolamine Triethanolamine 102-71-6 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

Fresh air, rest.

In case of skin contact

Remove contaminated clothes. Rinse and then wash skin with water and soap.

In case of eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

If swallowed

Give one or two glasses of water to drink.

4.2 Most important symptoms/effects, acute and delayed

Liquid may irritate eyes and skin. (USCG, 1999)

4.3 Indication of immediate medical attention and special treatment needed, if necessary

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Organic bases/amines and related compounds/

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.

5.2 Specific hazards arising from the chemical

Special Hazards of Combustion Products: Poisonous gases, such as NOx, may be produced (USCG, 1999)

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Collect leaking and spilled liquid in covered containers as far as possible. Then wash away with plenty of water.

6.3 Methods and materials for containment and cleaning up

ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Avoid breathing vapors, mist or gas. Environmental precautions: Do not let product enter drains. Methods and materials for containment and cleaning up: Keep in suitable, closed containers for disposal.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Separated from oxidants. Well closed. Dry.Keep container tightly closed in a dry and well-ventilated place. Hygroscopic.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state Colorless to light yellow, viscous liquid
Colour Viscous liquid
Odour Slight ammonical odor
Melting point/ freezing point 21ºC
Boiling point or initial boiling point and boiling range 190-193°C/5mmHg(lit.)
Flammability Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
Lower and upper explosion limit / flammability limit no data available
Flash point 179°C
Auto-ignition temperature 315.56°C
Decomposition temperature no data available
pH pH = 10.5 (0.1 N aqueous solution); strong base
Kinematic viscosity 590.5 cP at 25°C; 65.7 cP at 60°C
Solubility In water:soluble
Partition coefficient n-octanol/water (log value) log Kow = -1.00
Vapour pressure 0.01 mm Hg ( 20 °C)
Density and/or relative density 1.124g/mLat 25°C(lit.)
Relative vapour density 5.14 (vs air)
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Fire hazard: Combustible liquid when exposed to heat or flame.TRIETHANOLAMINE is an aminoalcohol. Neutralize acids to form salts plus water in exothermic reactions. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated in combination with strong reducing agents, such as hydrides. Reacts violently with strong oxidants. [Handling Chemicals Safely 1980. p. 928].

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

Incompatible materials: Acids, oxidizing agents.

10.6 Hazardous decomposition products

Hazardous decomposition products formed under fire conditions - Carbon oxides, nitrogen oxides (NOx).

11.Toxicological information

Acute toxicity

  • Oral: LD50 Mice oral 7400 mg/kg
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

Evaluation: There is inadequate evidence in humans for the carcinogenicity of triethanolamine. There is inadequate evidence in experimental animals for the carcinogenicity of triethanolamine. Overall evaluation: Triethanolamine is not classifiable as to its carcinogenicity to humans (Group 3).

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: LC50; Species: Pimephales promelas (fathead minnow); Conditions: flow-through bioassay with measured concentrations, 25.7°C, dissolved oxygen 7.3 g/L, and pH 7.8; Concentration: 11.8 g/L for 96 hr (95% confidence limit 10.6-13.0 g/L)
  • Toxicity to daphnia and other aquatic invertebrates: no data available
  • Toxicity to algae: EC50; Species: Scenedesmus subspicatus (Green algae); Conditions: tested in the Scenedesmus cell multiplication inhibition test, static; Concentration: 470,000 ug/L for 48 hr; Effect: decreased biomass
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

AEROBIC: Triethanolamine, present at 50 ppm, was biodegraded 70% ThOD (theoretical oxygen demand) in 10 days in a river die-away test using acclimated Kanawha River water as seed and sewage as inoculum(1). In a BOD test in water using a sewage inoculum, triethanolamine added at an initial concentration 2.5 ppm and run for 5, 10, 15 and 20 days exhibited 0, 0.8, 3.5 and 6.8% ThOD, respectively(2). Another BOD test in water using sewage inoculum incubated for 20 days resulted in 66% ThOD for triethanolamine(3). Using synthetic sea water and sewage inoculum, a 20 day run showed 69% ThOD for triethanolamine(3). Using effluent from a biological sanitary waste treatment plant as an inoculum, triethanolamine degradation was 5% ThOD (unadapted) and 28% ThOD (adapted) in a 5 day test(4). Triethanolamine, present at 500 ppm, added to BOD water with an activated sludge inoculum and acclimated for 15 days resulted in 22% ThOD after a 10 day test period(5).

12.3 Bioaccumulative potential

BCFs of <0.4 and <3.9 were reported using carp (Cyprinus carpio) which were exposed to respective concentrations of 2.5 and 25 ppm of triethanolamine over a 6-week period(1). According to a classification scheme(2), these BCFs suggest bioconcentration in aquatic organisms is low.

12.4 Mobility in soil

Using a structure estimation method based on molecular connectivity indices(1), the Koc of triethanolamine can be estimated to be 10(SRC). According to a classification scheme(2), this estimated Koc value suggests that triethanolamine is expected to have very high mobility in soil. The pKa of triethanolamine is 7.76(3), indicating that this compound will partially exist in cation form in the environment and cations generally adsorb more strongly to soils containing organic carbon and clay than their neutral counterparts(4).

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods.

14.2 UN Proper Shipping Name

ADR/RID: unknown
IMDG: unknown
IATA: unknown

14.3 Transport hazard class(es)

ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods.

14.4 Packing group, if applicable

ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods.

14.5 Environmental hazards

ADR/RID: no IMDG: no IATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
Triethanolamine Triethanolamine 102-71-6 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
EC Inventory Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Not Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
Vietnam National Chemical Inventory Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 17, 2017
Revision Date Aug 17, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
MSDS
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Name: 2-Chloroethyl vinyl ether ca. 95% (stabilized with MEHQ and Material Safety Data Sheet
Synonym: (2-Chloroethoxy)ethene; 2-Vinyloxyethyl chloride; Vinyl 2-chloroethyl ether
CAS: 102-71-6
Section 1 - Chemical Product   MSDS Name:2-Chloroethyl vinyl ether ca. 95% (stabilized with MEHQ and Material Safety Data Sheet
Synonym:(2-Chloroethoxy)ethene; 2-Vinyloxyethyl chloride; Vinyl 2-chloroethyl ether

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
102-71-6 2-Chloroethyl vinyl ether 95 203-799-6
Hazard Symbols: XN F
Risk Phrases: 11 22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Highly flammable. Harmful if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. Vapors may cause dizziness or suffocation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. May form explosive peroxides. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. If peroxide formation is suspected, do not open or move container. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat, sparks and flame.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. After opening, purge container with nitrogen before reclosing. Periodically test for peroxide formation on long-term storage. Addition of water or appropriate reducing materials will lessen peroxide formation.
Containers should be dated when opened and tested periodically for the presence of peroxides. Should crystals form in a peroxidizable liquid, peroxidation may have occurred and the product should be considered extremely dangerous. In this instance, the container should only be opened remotely by professionals. All peroxidizable substances should be stored away from heat and light and be protected from ignition sources.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 102-71-6: Belgium - TWA: 5 mg/m3 VLE Germany: 5 mg/m3 TWA (inhalable fraction) Malaysia: 5 mg/m3 TWA Netherlands: 5 mg/m3 MAC Spain: 5 mg/m3 VLA-ED CAS# 110-75-8: CAS# 150-76-5: Belgium - TWA: 5 mg/m3 VLE France - VME: 5 mg/m3 VME Germany: 5 mg/m3 TWA Malaysia: 5 mg/m3 TWA Netherlands: 5 mg/m3 MAC Spain: 5 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear slightly yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: 27 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 109 deg C @ 760 mm Hg
Freezing/Melting Point: -70 deg C
Autoignition Temperature: Not available.
Flash Point: 16 deg C ( 60.80 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.04 g/cm3
Molecular Formula: C4H7ClO
Molecular Weight: 106.55

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Under normal storage conditions, peroxidizable compounds can form and accumulate peroxides which may explode when subjected to heat or shock. This material is most hazardous when peroxide levels are concentrated by distillation or evaporation.
Conditions to Avoid:
Light, ignition sources, excess heat, mechanical shock.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, phosgene gas.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 102-71-6: KL9275000 CAS# 110-75-8: KN6300000 CAS# 150-76-5: SL7700000 LD50/LC50:
CAS# 102-71-6: Draize test, rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 10 mg Mild; Draize test, rabbit, skin: 560 mg/24H Mild; Oral, mouse: LD50 = 5846 mg/kg; Oral, rabbit: LD50 = 2200 mg/kg; Oral, rat: LD50 = 4920 uL/kg; Skin, rabbit: LD50 = >20 mL/kg; Skin, rat: LD50 = >16 mL/kg.
CAS# 110-75-8: Oral, rat: LD50 = 210 mg/kg; Skin, rabbit: LD50 = 2400 mg/kg.
CAS# 150-76-5: Draize test, rabbit, skin: 6 gm/12D (Intermittent) Mild; Draize test, rabbit, skin: 10%; Oral, rat: LD50 = 1600 mg/kg.
Carcinogenicity:
Triethanolamine - Not listed by ACGIH, IARC, or NTP.
2-Chloroethyl vinyl ether - Not listed by ACGIH, IARC, or NTP.
MEHQ - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish toxicity: LC50 (24-96 hr) bluegill sunfish 452-350 mg/l Invertebrate toxicity: LC50 (48 hr) contact Eisenia foetida 33 g/cm2 LC50 (14 days) absorbed in soil Eisenia foetida 740 mg/kg

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.*
Hazard Class: 3 (6.1)
UN Number: 1992
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3.2 (6.1)
UN Number: 1992
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3
UN Number: 1992
Packing group: II
USA RQ: CAS# 110-75-8: 1000 lb final RQ; 454 kg final RQ

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 102-71-6: 1
CAS# 110-75-8: No information available.
CAS# 150-76-5: 1
Canada
CAS# 102-71-6 is listed on Canada's DSL List.
CAS# 110-75-8 is listed on Canada's NDSL List.
CAS# 150-76-5 is listed on Canada's DSL List.
CAS# 102-71-6 is listed on Canada's Ingredient Disclosure List.
CAS# 110-75-8 is listed on Canada's Ingredient Disclosure List.
CAS# 150-76-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 102-71-6 is listed on the TSCA inventory.
CAS# 110-75-8 is listed on the TSCA inventory.
CAS# 150-76-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Spectrum
NMR Spectrum 1H NMR : 90 MHz in CDCl3
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IR Spectrum IR : liquid film
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Mass Spectrum Mass spectrum (electron ionization)
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Raman Spectrum Raman : 4880 A,200 M,liquid
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Toxicity
SKIN/EYE IRRITATION DATA
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Type of Test
Standard Draize test
Exposure Route
Administration onto the skin
Species Observed
Human
Dose/Duration
15 mg/3D (Intermittent)
Toxic Effects
--
Reference
Cutaneous Toxicity, Proceedings of the 3rd Conference, 1976, Drill, V.A., and P. Lazar, eds., New York, Academic Press, Inc. 1977 Volume(issue)/page/year: -,127,1977
SKIN/EYE IRRITATION DATA
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Type of Test
Standard Draize test
Exposure Route
Administration onto the skin
Species Observed
Rodent - rabbit
Dose/Duration
560 mg/24H
Toxic Effects
--
Reference
Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 19,276,1971
SKIN/EYE IRRITATION DATA
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Type of Test
Standard Draize test
Exposure Route
Administration into the eye
Species Observed
Rodent - rabbit
Dose/Duration
20 mg
Toxic Effects
--
Reference
American Journal of Ophthalmology. (Ophthalmic Pub. Co., 435 N. Michigan Ave., Suite 1415, Chicago, IL 60611) Series 3: V.1- 1918- Volume(issue)/page/year: 29,1363,1946

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