CAS No. 75-07-0

Formula: C2H4O
Basic Info

Acetaldehyde (systematic name ethanal) is an organic chemical compound with the formula CH3CHO, sometimes abbreviated by chemists as MeCHO (Me = methyl). It is one of the most important aldehydes, occurring widely in nature and being produced on a large scale in industry. Acetaldehyde occurs naturally in coffee, bread, and ripe fruit, and is produced by plants. It is also produced by the partial oxidation of ethanol by the liver enzyme alcohol dehydrogenase and may be a contributing factor to hangovers from alcohol consumption. Pathways of exposure include air, water, land, or groundwater, as well as drink and smoke. Consumption of disulfiram inhibits acetaldehyde dehydrogenase, the enzyme responsible for the metabolism of acetaldehyde, thereby causing it to build up in the body.
The International Agency for Research on Cancer (IARC) has listed acetaldehyde as a Group 1 carcinogen. Acetaldehyde is "one of the most frequently found air toxics with cancer risk greater than one in a million."

Molecular Weight
Exact Mass










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Appearance & Physical State
clear, colorless liquid
Boiling Point
Melting Point
Flash Point
Refractive Index
Water Solubility
> 500 g/L (20 ºC)
Stable, but air sensitive. Substances to be avoided include strong oxidizing agents, strong acids, reducing agents, alkalies, halogens, halogen oxides. Highly flammable. Vapour/air mixtures explosive over a very wide concentration range. May form peroxides
Storage Condition
Vapor Density
1.03 (vs air)
Vapor Pressure
52 mm Hg ( 37 °C)
Safety Info
Safety Statements
WGK Germany
Risk Statements
R12; R36/37; R40
HS Code
UN 1089
Hazard Class
Packing Group
Hazard Codes
SDS 1.0
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According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017


1.1 GHS Product identifier

Product name acetaldehyde

1.2 Other means of identification

Product number -
Other names FORMOL

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. The predominant use of acetaldehyde is as an intermediate in the synthesis of other chemicals. Acetaldehyde is used in the production of perfumes, polyester resins, and basic dyes. Acetaldehyde is also used as a fruit and fish preservative, as a flavoring agent, and as a denaturant for alcohol, in fuel compositions, for hardening gelatin, and as a solvent in the rubber, tanning, and paper industries.
Uses advised against no data available

1.4 Supplier's details

Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
Xuhui District, Shanghai, China
Telephone +86(21)64956998
Fax +86(21)54365166

1.5 Emergency phone number

Emergency phone number +86-400-6021-666
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Flammable liquids, Category 1

Eye irritation, Category 2

Specific target organ toxicity – single exposure, Category 3

Carcinogenicity, Category 2

2.2 GHS label elements, including precautionary statements

Signal word


Hazard statement(s)

H224 Extremely flammable liquid and vapour

H319 Causes serious eye irritation

H335 May cause respiratory irritation

H351 Suspected of causing cancer

Precautionary statement(s)

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P233 Keep container tightly closed.

P240 Ground and bond container and receiving equipment.

P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.

P242 Use non-sparking tools.

P243 Take action to prevent static discharges.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P264 Wash ... thoroughly after handling.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.


P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P370+P378 In case of fire: Use ... to extinguish.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P312 Call a POISON CENTER/doctor/…if you feel unwell.

P308+P313 IF exposed or concerned: Get medical advice/ attention.


P403+P235 Store in a well-ventilated place. Keep cool.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.


P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification


3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
acetaldehyde acetaldehyde 75-07-0 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

Fresh air, rest. Refer for medical attention.

In case of skin contact

Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .

In case of eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

If swallowed

Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .

4.2 Most important symptoms/effects, acute and delayed

Breathing vapors will be irritating and may cause nausea, vomiting, headache, and unconsciousness. Contact with eyes may cause burns and eye damage. Skin contact from clothing wet with the chemical causes burns or severe irritation. (USCG, 1999)

4.3 Indication of immediate medical attention and special treatment needed, if necessary

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Aldehydes and Related Compounds/

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Specific hazards arising from the chemical

Special Hazards of Combustion Products: Produces irritating vapor when heated Behavior in Fire: Vapors are heavier than air and may travel a considerable distance to a source of ignition and flash back. (USCG, 1999)

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Remove all ignition sources. Evacuate danger area! Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT absorb in saw-dust or other combustible absorbents. Remove vapour with fine water spray.

6.3 Methods and materials for containment and cleaning up

Accidental release measures. Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.; Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.; Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Fireproof. Separated from incompatible materials. See Chemical Dangers. Cooled. Keep in the dark. Store only if stabilized.Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8°C.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

NIOSH considers acetaldehyde to be a potential occupational carcinogen.

NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration.

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state clear, colorless liquid
Colour Volatile liquid or gas
Odour Pungent, fruity odor
Melting point/ freezing point -123ºC
Boiling point or initial boiling point and boiling range 21ºC
Flammability Class IA Flammable Liquid: Fl.P. below 22.78°C and BP below 37.78°C.Extremely flammable.
Lower and upper explosion limit / flammability limit Lower flammable limit: 4.0% by volume; Upper flammable limit: 60% by volume
Flash point -27ºC
Auto-ignition temperature 185°C; 148.89°C; 175°C (USCG, 1999)
Decomposition temperature no data available
pH no data available
Kinematic viscosity 0.253 mPa s at 9.5°C; 0.21 mPa s at 20°C
Solubility In water:> 500 g/L (20 ºC)
Partition coefficient n-octanol/water (log value) log Kow = -0.34
Vapour pressure 52 mm Hg ( 37 °C)
Density and/or relative density 0.788
Relative vapour density 1.03 (vs air)
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Avoid exposure to air any longer than necessary so as to prevent peroxide formation. Stable under recommended storage conditions. Test for peroxide formation before distillation or evaporation. Test for peroxide formation or discard after 1 year.

10.3 Possibility of hazardous reactions

Highly flammable liquid.The vapour is heavier than air and may travel along the ground; distant ignition possible.ACETALDEHYDE undergoes a vigorously exothermic condensation reaction in contact with strong acids, bases or traces of metals. Can react vigorously with oxidizing reagents such as dinitrogen pentaoxide, hydrogen peroxide, oxygen, silver nitrate, etc. Contamination often leads either to reaction with the contaminant or polymerization, both with the evolution of heat. Can react violently with acid anhydrides, alcohols, ketones, phenols, ammonia, hydrogen cyanide, hydrogen sulfide, halogens, phosphorus, isocyanates, concentrated sulfuric acid, and aliphatic amines. Reactions with cobalt chloride, mercury(II) chlorate or perchlorate form sensitive, explosive products [Sax, 9th ed., 1996, p. 5]. An oxygenation reaction of acetaldehyde in the presence of cobalt acetate at -20°C exploded violently when stirred. The event was ascribed to peroxyacetate formation [Phillips B. et al., J. Am. Chem. Soc., 1957, 79, p. 5982].

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

Incompatible materials: Oxidizing agents, reducing agents, acids, nitric acid, peroxides, bases, sodium hydroxide, amines, ammonia, oxygen. Warning: Acetaldehyde is oxidized rapidly and exothermically by air, to acetic acid, acid anhydrides, alcohols, halogens, ketones, phenol, hydrogen sulfide gas, hydrogen peroxide.

10.6 Hazardous decomposition products

Decomposes above 400°C to form ... methane & carbon monoxide.

11.Toxicological information

Acute toxicity

  • Oral: LD50 Rat oral 1930 mg/kg
  • Inhalation: LC50 Rat inhalation 37 g/cu m/30 min
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available


Acetaldehyde is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

Reproductive toxicity

No information is available on the reproductive or developmental effects of acetaldehyde in humans. Acetaldehyde has been shown, in animals, to cross the placenta to the fetus. Data from animal studies suggest that acetaldehyde may be a potential developmental toxin. In one study, a high incidence of embryonic resorptions was observed in mice injected with acetaldehyde. In rats exposed to acetaldehyde by injection, skeletal malformations, reduced birth weight, and increased postnatal mortality have been reported.

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: EC50; Species: Pimephales promelas (Fathead minnow); Conditions: flow-through bioassasy with measured concentrations, 23.9°C, dissolved oxygen 7.2 mg/L, hardness 53.0 mg/L calcium carbonate, alkalinity 43.2 mg/L calcium carbonate, and pH 7.63; Concentration: 30.8 mg/L for 96 hr (confidence limit 28.0-34.0 mg/L); Effect: loss of equilibrium
  • Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Waterflea); Conditions: static; Concentration: 42 mg/L for 48 hr; Effect: immobilization
  • Toxicity to algae: EC50; Species: Pseudokirchneriella subcapitata (Green algae) exponential growth phase, 15000 cells/mL, UTEX 1648; Conditions: static, 24°C, dissolved oxygen 1-2 mg/L; Concentration: 3359 ug/L for 48 hr; Effect: physiology, decreased photosynthesis
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

AEROBIC: Acetaldehyde, present at 100 mg/L, reached 80% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L and the Japanese MITI test which classified the compound as readily biodegradable(1). Acetaldehyde was also easily biodegraded by biological sewage treatment(2). Other laboratory screening tests confirm the biodegradability of acetaldehyde by acclimated sludge and sewage(3-7) with theoretical BODs of 28% in 24 hr(3), 100% in 5 hr(4), 40.5% in 5 days(8), and 70% in 5 days(5). Acetaldehyde was oxidized in a silty clay loam but no rates were given(9). In a die-away test in seawater, acetaldehyde concentrations declined to approximately 25% of initial values in 1 hr, whereas no decline in concentration was observed in sterile controls(10).

12.3 Bioaccumulative potential

An estimated BCF of 3 was calculated in fish for acetaldehyde(SRC), using a log Kow of -0.34(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

12.4 Mobility in soil

Using a structure estimation method based on molecular connectivity indices(1), the Koc of acetaldehyde can be estimated to be 1(SRC). According to a classification scheme(2), this estimated Koc value suggests that acetaldehyde is expected to have very high mobility in soil.

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods


The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN1089 IMDG: UN1089 IATA: UN1089

14.2 UN Proper Shipping Name


14.3 Transport hazard class(es)


14.4 Packing group, if applicable


14.5 Environmental hazards

ADR/RID: no IMDG: no IATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
acetaldehyde acetaldehyde 75-07-0 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
EC Inventory Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
Vietnam National Chemical Inventory Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 17, 2017
Revision Date Aug 17, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%


  • IPCS - The International Chemical Safety Cards (ICSC), website:
  • HSDB - Hazardous Substances Data Bank, website:
  • IARC - International Agency for Research on Cancer, website:
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website:
  • CAMEO Chemicals, website:
  • ChemIDplus, website:
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website:
  • Germany GESTIS-database on hazard substance, website:
  • ECHA - European Chemicals Agency, website:

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
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Name: Acetaldehyde 99.5% Material Safety Data Sheet
Synonym: Acetic aldehyde; Acetylaldehyde; Ethylaldehyde; Ethanal
CAS: 75-07-0
Section 1 - Chemical Product   MSDS Name:Acetaldehyde 99.5% Material Safety Data Sheet
Synonym:Acetic aldehyde; Acetylaldehyde; Ethylaldehyde; Ethanal

CAS# Chemical Name content EINECS#
75-07-0 Acetaldehyde > 99.5 200-836-8
Hazard Symbols: XN F+
Risk Phrases: 12 36/37 40

Extremely flammable. Irritating to eyes and respiratory system.
Possible risks of irreversible effects.Lachrymator (substance which increases the flow of tears).
Potential Health Effects
Causes severe eye irritation. Vapors may cause eye irritation.
May cause transient corneal injury. Lachrymator (substance which increases the flow of tears).
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed. May cause central nervous system depression.
Causes respiratory tract irritation. May cause narcotic effects in high concentration. Exposure produces central nervous system depression. Vapors may cause dizziness or suffocation. Can produce delayed pulmonary edema. Inhalation of large amounts may cause respiratory stimulation, followed by respiratory depression, convulsions and possible death due to respiratory paralysis.
Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye contact may cause conjunctivitis. Prolonged skin contact may cause erythema (redness) and burns. Long-term inhalation studies of acetaldehyde produced laryngeal cancers in hamsters and nasal cancers in rats.

  Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes. Get medical aid if symptoms occur. Wash clothing before reuse.
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Persons with kidney disease, chronic respiratory disease, liver disease, or skin disease may be at increased risk from exposure to this substance. Treat symptomatically and supportively.
Antidote: None reported.

  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Vapors may form an explosive mixture with air. Use water spray to keep fire-exposed containers cool. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Extremely flammable liquid and vapor. Vapor may cause flash fire. Forms peroxides of unknown stability. Containers may explode in the heat of a fire. Will be easily ignited by heat, sparks or flame. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Sensitivity to mechanical impact: Yes, if peroxides are formed. Closed containers exposed to heat may explode. Sensitive to static discharge.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Water may be ineffective. Do NOT use straight streams of water.

  General Information: Use proper personal protective equipment as indicated in Section 8.
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Use water spray to disperse the gas/vapor.
Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Place under an inert atmosphere. U.S. regulations require reporting spills and releases to soil, water and air in excess of reportable quantities.

Section 7 - HANDLING and STORAGE
Ground and bond containers when transferring material. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Take precautionary measures against static discharges. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Handle under an inert atmosphere. Store protected from air. This product may be under pressure; cool before opening. If peroxide formation is suspected, do not open or move container. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation.
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep from freezing. Store in a tightly closed container.
Keep from contact with oxidizing materials. Keep away from strong acids. Refrigerator/flammables. Keep away from reducing agents. Do not expose to air. Store in explosion-proof refrigerator. After opening, purge container with nitrogen before reclosing.
Periodically test for peroxide formation on long-term storage.
Addition of water or appropriate reducing materials will lessen peroxide formation. Store under an inert atmosphere.

  Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear chemical goggles.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Physical State: Liquid
Appearance: clear, colorless
Odor: pungent odor - fruity odor
pH: Not available.
Vapor Pressure: 750 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 20 - 21 deg C @ 760 mm Hg
Freezing/Melting Point: -123.5 deg C
Autoignition Temperature: 175 deg C ( 347.00 deg F)
Flash Point: -38 deg C ( -36.40 deg F)
Explosion Limits, lower: 4.0 vol %
Explosion Limits, upper: 60.0 vol %
Decomposition Temperature: > 400 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 0.788 g/cm3 @ 16C
Molecular Formula: C2H4O
Molecular Weight: 44.05

  Chemical Stability:
Unstable in air. May undergo autopolymerization. Forms explosive peroxides on prolonged storage and exposure to air. Polymerizes violently in the presence of traces of metals or acids.
Conditions to Avoid:
Ignition sources, exposure to air, heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, acids, strong bases, alcohols, amines, ammonia, halogens, phenols, phosphorus, isocyanates, acid anhydrides, hydrogen sulfide, air, ketones, hydrogen cyanide, cobalt chloride, mercury (II) chlorate, mercury (II) perchlorate, trace metals.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, methane.
Hazardous Polymerization: May occur.

CAS# 75-07-0: AB1925000 LD50/LC50:
CAS# 75-07-0: Draize test, rabbit, eye: 40 mg Severe; Inhalation, mouse: LC50 = 23 gm/m3/4H; Inhalation, rat: LC50 = 13300 ppm/4H; Oral, mouse: LD50 = 900 mg/kg; Oral, rat: LD50 = 661 mg/kg; Skin, rabbit: LD50 = 3540 mg/kg.
Acetaldehyde - ACGIH: A3 - Animal Carcinogen California: carcinogen; initial date 4/1/88 NIOSH: occupational carcinogen NTP: Suspect carcinogen OSHA: Possible Select carcinogen IARC: Group 2B carcinogen Other:
See actual entry in RTECS for complete information.

Fish: Fathead Minnow: EC50 = 30.8-37.2 mg/L; 96 Hr; Flow-through at 21.6-23.9C (pH 7.1-7.63)Fish: Bluegill/Sunfish: LC50 = 53 mg/L; 96 Hr; UnspecifiedWater flea Daphnia: EC50 = 9000-14000 mg/L; 48 Hr; UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 =280.6-403.5 mg/L; 5,15,25 min; Unspecified

  Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Hazard Class: 3
UN Number: 1089
Packing Group: I
Hazard Class: 3.1
UN Number: 1089
Packing Group: I
Dangerous Goods Code: 3(1A)
UN Number: 1089

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F+
Risk Phrases:
R 12 Extremely flammable.
R 36/37 Irritating to eyes and respiratory system.
R 40 Possible risks of irreversible effects.
Safety Phrases:
S 16 Keep away from sources of ignition - No
S 33 Take precautionary measures against static
S 36/37 Wear suitable protective clothing and
WGK (Water Danger/Protection)
CAS# 75-07-0: 1
United Kingdom Occupational Exposure Limits
CAS# 75-07-0: OES-United Kingdom, TWA 20 ppm TWA; 37 mg/m3 TWA
CAS# 75-07-0: OES-United Kingdom, STEL 50 ppm STEL; 92 mg/m3 STEL
CAS# 75-07-0 is listed on Canada's DSL List.
CAS# 75-07-0 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 75-07-0: OEL-ARAB Republic of Egypt:TWA 100 ppm (180 mg/m3)
OEL-AUSTRALIA:TWA 100 ppm (180 mg/m3);STEL 150 pp (270 mg/m3)
OEL-BELGIUM:TWA 100 ppm (180 mg/m3);STEL 150 ppm (270 mg/m3)
OEL-DENMARK:TWA 25 ppm (45 mg/m3)
OEL-FINLAND:TWA 50 ppm (90 mg/m3);STEL 75 ppm (13 mg/m3)
OEL-FRANCE:TWA 100 ppm (180 mg/m3)
OEL-GERMANY:TWA 50 ppm (90 mg/m3);Carcinogen JAN9
OEL-HUNGARY:STEL 25 mg/m3;Carcinogen
OEL-INDIA:TWA 100 ppm (180 mg/m3);STEL 150 ppm (270 mg/m3)
OEL-THE NETHERLANDS:TWA 100 ppm (180 mg/m3)
OEL-THE PHILIPPINES:TWA 200 ppm (360 mg/m3)
OEL-RUSSIA:STEL 5 mg/m3;Skin
OEL-SWEDEN:TWA 25 ppm (45 mg/m3);STEL 50 ppm (90 mg/m3)
OEL-SWITZERLAND:TWA 50 ppm (90 mg/m3);STEL 100 pp (180 mg/m3)
OEL-TURKEY:TWA 200 ppm (360 mg/m3)
OEL-UNITED KINGDOM:TWA 100 ppm (180 mg/m3);STEL 150 ppm
CAS# 75-07-0 is listed on the TSCA inventory.

NMR Spectrum 1H NMR : parameter in CDCl3
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IR Spectrum IR : liquid film
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Mass Spectrum Mass spectrum (electron ionization)
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UV Spectrum UV/Visible spectrum
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