dicloran

CAS No. 99-30-9

Formula: C6H4Cl2N2O2
Basic Info

Dichloran is a component for pesticide formulations.

Formula
C6H4Cl2N2O2
Molecular Weight
207.014
Exact Mass
205.965
LogP
3.5882
PSA
71.84
Synonyms

2,6-dichloro-4-nitroaniline

Dicloran

1-amino-2,6-dichloro-4-nitrobenzene

Bortran

CDNA

2,6-dichloro-4-nitrobenzenamine

Allisan

DCNA

4-nitro-2,6-dichloroaniline

2,6-dichloro-p-nitroaniline

Benzenamine, 2,6-dichloro-4-nitro-

Ditranil

Botran

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Properties
Appearance & Physical State
yellow needle crystal
Density
1.624g/cm3
Boiling Point
350ºC (Decomposes)
Melting Point
187-192ºC
Flash Point
149.1ºC
Refractive Index
1.655
Water Solubility
1 g/L (60 ºC)
Stability
Stable under normal temperatures and pressures.
Storage Condition
0-6ºC
Safety Info
RTECS
BX2975000
Safety Statements
S26-S37/39
WGK Germany
3
Risk Statements
R36/37/38
HS Code
2921420090
RIDADR
2811
Hazard Class
6.1(b)
Packing Group
III
Hazard Codes
MSDS
SDS 1.0
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SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name dicloran

1.2 Other means of identification

Product number -
Other names 2,6-dichloro-4-nitroaniline

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
Xuhui District, Shanghai, China
Telephone +86(21)64956998
Fax +86(21)54365166

1.5 Emergency phone number

Emergency phone number +86-400-6021-666
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Acute toxicity - Oral, Category 2

Acute toxicity - Dermal, Category 1

Acute toxicity - Inhalation, Category 2

Specific target organ toxicity – repeated exposure, Category 2

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Danger

Hazard statement(s)

H300 Fatal if swallowed

H310 Fatal in contact with skin

H330 Fatal if inhaled

H373 May cause damage to organs through prolonged or repeated exposure

H411 Toxic to aquatic life with long lasting effects

Precautionary statement(s)
Prevention

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P262 Do not get in eyes, on skin, or on clothing.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P284 [In case of inadequate ventilation] wear respiratory protection.

P273 Avoid release to the environment.

Response

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/…

P321 Specific treatment (see ... on this label).

P330 Rinse mouth.

P302+P352 IF ON SKIN: Wash with plenty of water/...

P310 Immediately call a POISON CENTER/doctor/…

P361+P364 Take off immediately all contaminated clothing and wash it before reuse.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P320 Specific treatment is urgent (see ... on this label).

P314 Get medical advice/attention if you feel unwell.

P391 Collect spillage.

Storage

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
dicloran dicloran 99-30-9 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

Fresh air, rest.

In case of skin contact

Remove contaminated clothes. Rinse and then wash skin with water and soap.

In case of eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

If swallowed

Rinse mouth.

4.2 Most important symptoms/effects, acute and delayed

SYMPTOMS: Symptoms of exposure to this compound may include irritation of the nose, eyes, skin and throat, coughing, chest discomfort, nausea and vomiting. Absorption into the body leads to the formation of methemoglobin which in sufficient concentrations causes cyanosis. Exposure to this compound may also cause sensitization and bladder irritation.

4.3 Indication of immediate medical attention and special treatment needed, if necessary

Gastrointestinal decontamination. If a large amount of the fungicide has been ingested in the last few hours, and if copious vomiting has not already occurred, it may be reasonable to consider GI decontamination. Activated charcoal can be used along with the addition of the cathartic sorbitol to the charcoal slurry. If sorbitol is given separately, it should be diluted with an equal volume of water before administration. No more than one dose of sorbitol is recommended and it should be used with caution in children and the elderly. If contact with the toxicant has been minimal (for example, oral contamination only, promptly flushed out of the mouth), administration of charcoal without a cathartic, followed by careful observation of the patient, probably represents optimal management. /Substituted benzenes/

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Appropriate Extinguishing Media: water spray, Class A, B or C extinguisher. /Botran 5F Fungicide/

5.2 Specific hazards arising from the chemical

Flash point data for this chemical are not available; however, it is probably combustible.

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT wash away into sewer. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.

6.3 Methods and materials for containment and cleaning up

Do not contaminate /receiving/ water when disposing of equipment, washwaters or rinsate. /Botran 5F Fungicide/

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs.Do not contaminate water, food or feed by storage ... Store in original container and keep closed. Store in a cool, dry place. /Botran 5F Fungicide/

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state yellow needle crystal
Colour Yellow needles from alcohol and acetic acid
Odour Odorless
Melting point/ freezing point -46°C(lit.)
Boiling point or initial boiling point and boiling range 130°C/2.3mmHg(lit.)
Flammability Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
Lower and upper explosion limit / flammability limit no data available
Flash point 64°C(lit.)
Auto-ignition temperature no data available
Decomposition temperature no data available
pH no data available
Kinematic viscosity no data available
Solubility In water:1 g/L (60 ºC)
Partition coefficient n-octanol/water (log value) log Kow = 2.80 at 25°C
Vapour pressure 1.2e-06 mm Hg at 20°C
Density and/or relative density 1.624g/cm3
Relative vapour density no data available
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

STABLE TO HYDROLYSIS & OXIDATION

10.3 Possibility of hazardous reactions

... NON-FLAMMABLEDust explosion possible if in powder or granular form, mixed with air.DICHLORAN is incompatible with acids, acid chlorides, acid anhydrides, and strong oxidizing agents .

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

no data available

10.6 Hazardous decomposition products

When heated to decomposition it emits toxic fumes of /hydrogen chloride and nitrogen oxides/.

11.Toxicological information

Acute toxicity

  • Oral: LD50 Guinea pig oral 1450 mg/kg
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: LC50; Species: Lepomis macrochirus (Bluegill); Conditions: freshwater, static; Concentration: 37000 ug/L for 96 hr
  • Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water flea) age <24 hr; Conditions: freshwater, static; Concentration: 2070 ug/L for 48 hr (95% confidence interval: 1800-2400 ug/L) /97% purity formulation
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

(14)C-Labeled CO2 was evolved when labeled 2,6-dichloro-4-nitroaniline was applied to silt loam soils which had been receiving 2,6-dichloro-4-nitroaniline fungicide applications for several years(1,2); the rate of degradation was observed to increase as new additions of 2,6-dichloro-4-nitroaniline were applied to these soils over a period of several weeks(1,2); sterilization of these soils by steam, sodium azide, silver nitrate or mercuric chloride inhibited the decomposition completely(2); applications of 2,6-dichloro-4-nitroaniline to a soil which had not received previous applications evolved no labeled CO2(1,2). Over an incubation period of 1-2 months in both anaerobic (flooded) and aerobic soil conditions in three different CA soils, the degradation rate of 2,6-dichloro-4-nitroaniline was observed to be 2.5 to over 20 times faster in non-sterile soil versus sterile soil suggesting that microbial degradation is the major degradation process in soil(3).

12.3 Bioaccumulative potential

2,6-Dichloro-4-nitroaniline has a moderate potential to bio-accumulate in fish tissue based on a bioconcentration study which indicated a bioconcentration factor (BCF) of 136 in whole fish tissue(1); however, the bioaccumulated residues were almost completely eliminated from fish tissues (86-98%) during a 7-14 day depuration period(1). An estimated BCF of 33 can be calculated in fish for 2,6-dichloro-4-nitroaniline(SRC), using a log Kow of 2.80(2) and a regression-derived equation(3). According to a classification scheme(4), a BCF of 33 suggests the potential for bioconcentration in aquatic organisms is moderate(SRC).

12.4 Mobility in soil

Measured Koc values for 2,6-dichloro-4-nitroaniline in a variety of soils are reported to range from 660 to 1100(1). A 2,6-dichloro-4-nitroaniline Koc value of 1000, based on measured data, is recommended for developing QSAR estimation methods(2). According to a classification scheme(3), these Koc values suggests that 2,6-dichloro-4-nitroaniline is expected to have low mobility in soil. Mobility is expected to increase in coarser soils(4).

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN2735 IMDG: UN2735 IATA: UN2735

14.2 UN Proper Shipping Name

ADR/RID: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S.
IMDG: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S.
IATA: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S.

14.3 Transport hazard class(es)

ADR/RID: 8 IMDG: 8 IATA: 8

14.4 Packing group, if applicable

ADR/RID: III IMDG: III IATA: III

14.5 Environmental hazards

ADR/RID: yes IMDG: yes IATA: yes

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
dicloran dicloran 99-30-9 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
EC Inventory Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Not Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
Vietnam National Chemical Inventory Not Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 12, 2017
Revision Date Aug 12, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
MSDS
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Name: 2 6-Dichloro-4-nitroaniline 95%(tlc) Material Safety Data Sheet
Synonym: Resisa
CAS: 99-30-9
Section 1 - Chemical Product   MSDS Name:2 6-Dichloro-4-nitroaniline 95%(tlc) Material Safety Data Sheet
Synonym:Resisa

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
99-30-9 2,6-Dichloro-4-nitroaniline 95% 202-746-4
Hazard Symbols: XN
Risk Phrases: 22

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful if swallowed.
Potential Health Effects
Eye:
Causes eye irritation. May result in corneal injury.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, and death. Effects may be delayed 2 to 4 hours.
Inhalation:
Causes respiratory tract irritation. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, tachycardia, dyspnea (labored breathing), and death. Damage may be delayed.
Chronic:
Absorption into the body leads to the formation of methemoglobin which in sufficient concentrations causes cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood).

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, observing precautions in the Protective Equipment section.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Do not breathe dust, vapor, mist, or gas.
Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 99-30-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 190 - 192 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >350 deg C
Solubility in water: 1 g/l water (60c)
Specific Gravity/Density:
Molecular Formula: C6H4Cl2N2O2
Molecular Weight: 207.02

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong acids - acid chlorides - acid anhydrides.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 99-30-9: BX2975000 LD50/LC50:
CAS# 99-30-9: Inhalation, rat: LC50 = >21600 mg/m3/1H; Oral, mouse: LD50 = 1500 mg/kg; Oral, rat: LD50 = 2400 mg/kg; Skin, rabbit: LD50 = >2 gm/kg.
Carcinogenicity:
2,6-Dichloro-4-nitroaniline - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 99-30-9: 2
Canada
CAS# 99-30-9 is listed on Canada's NDSL List.
CAS# 99-30-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 99-30-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Spectrum
NMR Spectrum 1H NMR : Predict
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Mass Spectrum Mass spectrum (electron ionization)
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Analysis Methods
Kovats' RI, non-polar column, temperature ramp
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Column Shape
Capillary
Active Phase(℃)
DB-1
Retention index
1716.
Temperature Control
Method
temperature ramp
Comments
He, 6. K/min; Column length: 15. m; Column diameter: 0.25 mm; T<sub>start</sub>: 100. C; T<sub>end</sub>: 270. C
Reference
Hall, G.L.Whitehead, W.E.Mourer, C.R.Shibamoto, T.A new gas chromatographic retention index for pesticides and related compoundsJ. Hi. Res. Chromatogr. Chromatogr. Comm.1986, 9, 5, 266-271.
Kovats' RI, non-polar column, temperature ramp
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Column Shape
Capillary
Active Phase(℃)
DB-5
Retention index
1731.
Temperature Control
Method
temperature ramp
Comments
He, 6. K/min; Column length: 15. m; Column diameter: 0.25 mm; T<sub>start</sub>: 100. C; T<sub>end</sub>: 270. C
Reference
Hall, G.L.Whitehead, W.E.Mourer, C.R.Shibamoto, T.A new gas chromatographic retention index for pesticides and related compoundsJ. Hi. Res. Chromatogr. Chromatogr. Comm.1986, 9, 5, 266-271.
Van Den Dool and Kratz RI, non-polar column, temperature ramp
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Column Shape
Capillary
Active Phase(℃)
SLB-5MS
Retention index
1717.
Temperature Control
Method
temperature ramp
Comments
30. m/0.25 mm/0.25 μm, He, 2. K/min; T<sub>start</sub>: 70. C; T<sub>end</sub>: 300. C
Reference
Mondello, L.Casilli, A.Tranchida, P.Q.Presti, M.L.Dugo, P.Dugo, G.Comprehensive gas chromatography coupled to mass spectrometry for the separation of pesticides in a very complex matrixAnal. Bioanal. Chem.2007, 389, 6, 1755-1763.
Van Den Dool and Kratz RI, non-polar column, temperature ramp
expand collapse
Column Shape
Capillary
Active Phase(℃)
SLB-5MS
Retention index
1723.
Temperature Control
Method
temperature ramp
Comments
30. m/0.25 mm/0.25 μm, He, 2. K/min; T<sub>start</sub>: 70. C; T<sub>end</sub>: 300. C
Reference
Mondello, L.Casilli, A.Tranchida, P.Q.Presti, M.L.Dugo, P.Dugo, G.Comprehensive gas chromatography coupled to mass spectrometry for the separation of pesticides in a very complex matrixAnal. Bioanal. Chem.2007, 389, 6, 1755-1763.
Normal alkane RI, non-polar column, custom temperature program
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Column Shape
Capillary
Active Phase(℃)
5 % Phenyl methyl siloxane
Retention index
1734.
Temperature Control
Method
custom temperature program
Comments
30. m/0.25 mm/0.25 μm, Helium; Program: 50 0C(1 min) <sup> </sup>25 0C/min -&gt; 125 0C <sup> </sup>10 0C/min -&gt; 300 0C (10 min)
Reference
Department of Food Safety, Ministry of HealthWelfareAnalytical methods for residual compositional substances of agricultural chemicals, feed aadditives, and veterinary drugs in foods2006, retrieved from http://www.mhlw.go.jp/english/topics/foodsafety/positivelist060228/de/060526-1a.pdf.
Synthesis Route

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