4-nitrophenol

CAS No. 100-02-7

Formula: C6H5NO3
Basic Info

4-Nitrophenol (also called p-nitrophenol or 4-hydroxynitrobenzene) is a phenolic compound that has a nitro group at the opposite position of hydroxyl group on the benzene ring.

Formula
C6H5NO3
Molecular Weight
139.109
Exact Mass
139.027
LogP
1.8236
PSA
66.05
Synonyms

p-Nitrophenol

4-Nitrophenol

Phenol, 4-nitro-

expand collapse

Properties
Appearance & Physical State
yellow to brown crystals
Density
1.481
Boiling Point
279ºC
Melting Point
112-114ºC
Flash Point
169ºC
Water Solubility
1.6 g/100 mL (25 ºC)
Stability
Stable. Incompatible with strong oxidizing agents, strong bases, organics, combustible material, reducing agents. Combustible.
Storage Condition
Store in dark
Vapor Pressure
0.6 mm Hg ( 120 °C)
Safety Info
RTECS
SM2275000
Safety Statements
S28
WGK Germany
2
Risk Statements
R20/21/22; R33
HS Code
2908991010
RIDADR
UN 1663 6.1/PG 3
Hazard Class
6.1
Packing Group
III
Caution Statement
P260; P280
Hazard Codes
Hazard Declaration
Caution Statement
MSDS
SDS 1.0
expand collapse
Download/Modify | Technical supported by XiXisys.com. For US version, EU version (23 languages) and more, please refer to xixisys.com/en/sds/search

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-nitrophenol

1.2 Other means of identification

Product number -
Other names 4-Nitrophenol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. 4-Nitrophenol is used to manufacture drugs (e.g., acetaminophen), fungicides, methyl and ethyl parathion insecticides, and dyes and to darken leather.
Uses advised against no data available

1.4 Supplier's details

Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
Xuhui District, Shanghai, China
Telephone +86(21)64956998
Fax +86(21)54365166

1.5 Emergency phone number

Emergency phone number +86-400-6021-666
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Acute toxicity - Oral, Category 4

Acute toxicity - Dermal, Category 4

Acute toxicity - Inhalation, Category 4

Specific target organ toxicity – repeated exposure, Category 2

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Warning

Hazard statement(s)

H302 Harmful if swallowed

H312 Harmful in contact with skin

H332 Harmful if inhaled

Precautionary statement(s)
Prevention

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

Response

P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/…if you feel unwell.

P330 Rinse mouth.

P302+P352 IF ON SKIN: Wash with plenty of water/...

P312 Call a POISON CENTER/doctor/…if you feel unwell.

P321 Specific treatment (see ... on this label).

P362+P364 Take off contaminated clothing and wash it before reuse.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P314 Get medical advice/attention if you feel unwell.

Storage

none

Disposal

P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
4-nitrophenol 4-nitrophenol 100-02-7 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

Fresh air, rest. Refer for medical attention.

In case of skin contact

Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .

In case of eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

If swallowed

Rinse mouth. Rest. Refer for medical attention .

4.2 Most important symptoms/effects, acute and delayed

Inhalation or ingestion causes headache, drowsiness, nausea, and blue color in lips, ears, and fingernails (cyanosis). Contact with eyes or skin causes irritation; can be absorbed through skin to give same symptoms as for inhalation. (USCG, 1999)

4.3 Indication of immediate medical attention and special treatment needed, if necessary

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Dinitrophenol and Related Compounds/

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, dry chemical, foam, or carbon dioxide. Use water spray to keep fire-exposed containers cool. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Fight fire from protected location or maximum possible distance.

5.2 Specific hazards arising from the chemical

Special Hazards of Combustion Products: Toxic oxides of nitrogen and fumes of unburned material may form in fires. Behavior in Fire: Decomposes violently at 279°C and will burn even in absence of air. (USCG, 1999)

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.

6.3 Methods and materials for containment and cleaning up

Spill or leak procedures: Shovel into suitable dry container.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Separated from combustible substances, reducing agents and food and feedstuffs. Well closed.... KEEP ALL FLAMMABLES AWAY FROM AREA WHERE OXIDIZING AGENTS ARE STORED. ... AREA ... KEPT COOL & VENTILATED, & SHOULD BE FIREPROOFED.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state yellow to brown crystals
Colour Colorless to slightly yellow crystals
Odour Odorless
Melting point/ freezing point 98°C(lit.)
Boiling point or initial boiling point and boiling range 279°C(lit.)
Flammability Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
Lower and upper explosion limit / flammability limit no data available
Flash point 169°C
Auto-ignition temperature 282.78°C
Decomposition temperature at 279°C°C
pH no data available
Kinematic viscosity no data available
Solubility In water:1.6 g/100 mL (25 ºC)
Partition coefficient n-octanol/water (log value) no data available
Vapour pressure 0.6 mm Hg ( 120 °C)
Density and/or relative density 1.481
Relative vapour density 1.244 at 65°C (Relative to Air)
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

... Will burn even in absence of air.Dust explosion possible if in powder or granular form, mixed with air.4-NITROPHENOL is a slightly yellow, crystalline material, moderately toxic. Mixtures with diethyl phosphite may explode when heated. Decomposes exothermally, emits toxic fumes of oxides of nitrogen [Lewis, 3rd ed., 1993, p. 941]. Decomposes violently at 279°C and will burn even in absence of air (USCG, 1999). Solid mixtures of the nitrophenol and potassium hydroxide (1:1.5 mol) readily deflagrate [Bretherick, 5th Ed., 1995].

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

Mixtures with diethyl phosphite may explode when heated.

10.6 Hazardous decomposition products

DECOMPOSES VIOLENTLY @ 279 DEG C ...

11.Toxicological information

Acute toxicity

  • Oral: LD50 Rat (male) oral 191 mg/kg (95% confidence limits 131-303 mg/kg)
  • Inhalation: LD50 Rat inhalation > 4.7 mg/L/4 hours
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

Cancer Classification: Group D Not Classifiable as to Human Carcinogenicity

Reproductive toxicity

No information is available on the reproductive or developmental effects of 4-nitrophenol in humans. One animal study reported no histological alterations in the testes and epididymides in mice exposed to 4-nitrophenol by inhalation, while in another study no changes were observed in the reproductive index of pregnant mice given 4-nitrophenol by gavage (placing the chemical experimentally in the stomach).

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: LC50; Species: Lepomis macrochirus (bluegill); Conditions: static, unmeasured; Concentration: 8,280 ug/L for 24 hr
  • Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water flea); Conditions: freshwater, renewal, 25°C, pH >7; Concentration: 8000 ug/L for 24 hr; Effect: behavior, equilibrium /formulation
  • Toxicity to algae: EC50; Species: Chlorococcum sp. (Green Algae); Conditions: freshwater, static; Concentration: 5 umol/L for 9 days; Effect: population changes, general /formulation
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

PURE CULTURE: Pseudomonas strains capable of mineralizing 2,4-dichlorophenol and p-nitrophenol (PNP) in culture media were isolated from soil. A Pseudomonas able to mineralize 5.0 ug p-nitrophenol/mL in culture did not mineralize the compound in sterile or nonsterile lake water. The bacterium destroyed p-nitrophenol in sterile sewage and enhanced p-nitrophenol mineralization in nonsterile sewage. When added to the surface of sterile soil, the bacterium mineralized little of the p-nitrophenol present at 5.0 ug/g, but it was active if mixed well with the sterile soil.[Goldstein RM et al; Appl Environ Microbiol 50 (4): 977-83 (1985)] Full text: PMC291779

12.3 Bioaccumulative potential

BCF values of 2.5 to 7.8 were measured for carp (Carprinus carpio) exposed to 0.02 ppm and 0.2 ppm 4-nitrophenol over a 6-8 week incubation period(1). The BCF value of 4-nitrophenol was reported as 79 in fathead minnows(2) and 58 in golden orfe(3). According to a classification scheme(4), these BCF values suggest bioconcentration in aquatic organisms is low to moderate.

12.4 Mobility in soil

The sorption of benzoic acid, nitrobenzene, 4-nitrophenol, 2,4-dichlorophenoxyacetic acid, and naphthalene was determined for 10 Danish soils in laboratory studies(1); measured equilibrium isotherms were of nonlinear Freundlich type for nearly all combinations of soil test compounds(1); adsorption was significantly correlated with the organic carbon content of the soils tested(1); Koc values in the 10 soils ranged from 56 to 530 with an average Koc 210(1); no significant correlations with pH and cation exchange capacity were observed(1). The Koc of 4-nitrophenol was reported as 55 in Brookston clay loam(2) and a log Koc of 1.7 was reported in a second study(3). The increasing content of copper in two Chinese soils was shown to limit 4-nitrophenol adsorption(4). In sorption studies using peat, 4-nitrophenol had measured Koc values of 96 (when 4-nitrophenol was in the neutral state) and 16 (when 4-nitrophenol existed as anionic species)(5). Using a reference soil from Germany, 4-nitrophenol had Koc value of 148 in a soil column leaching test(6). A Koc of 26 was measured in one sediment sample from China(7). A median literature Koc value of 234 (log Koc = 2.37) has been reported for 4-nitrophenol which can be used to develop QSAR estimations(8). According to a classification scheme(9), a median Koc value of 234 suggests that 4-nitrophenol is expected to have moderate mobility in soil. However, the experimental Koc range extends from 16 to over 500 suggesting a range of very high mobility to low mobility(SRC). The pKa of 4-nitropehnol is 7.15(10), indicating that this compound will exist partially in anion form in the environment and anions generally do not adsorb more strongly to soils containing organic carbon and clay than their neutral counterparts(11).

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN1663 IMDG: UN1663 IATA: UN1663

14.2 UN Proper Shipping Name

ADR/RID: NITROPHENOLS (o-, m-, p-)
IMDG: NITROPHENOLS (o-, m-, p-)
IATA: NITROPHENOLS (o-, m-, p-)

14.3 Transport hazard class(es)

ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1

14.4 Packing group, if applicable

ADR/RID: III IMDG: III IATA: III

14.5 Environmental hazards

ADR/RID: no IMDG: no IATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
4-nitrophenol 4-nitrophenol 100-02-7 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
EC Inventory Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
Vietnam National Chemical Inventory Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 10, 2017
Revision Date Aug 10, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
MSDS
expand collapse
Name: 4-Nitrophenol Material Safety Data Sheet
Synonym: 4-Hydroxynitrobenzen
CAS: 100-02-7
Section 1 - Chemical Product   MSDS Name:4-Nitrophenol Material Safety Data Sheet
Synonym:4-Hydroxynitrobenzen

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
100-02-7 4-Nitrophenol >98% 202-811-7
Hazard Symbols: XN
Risk Phrases: 20/21/22 33

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Danger of cumulative effects.Light sensitive.
Potential Health Effects
Eye:
May cause eye irritation. Causes redness and pain.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Causes symptoms similar to those of inhalation. Causes redness and pain. Substance is readily absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, and death.
May cause effects similar to those for inhalation exposure. Effects may be delayed 2 to 4 hours. Methemoglobinemia is characterized by dizziness, drowsiness, headache, shortness of breath, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), rapid heart rate and chocolate-brown colored blood.
Inhalation:
Harmful if inhaled. May cause cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood). May cause respiratory tract irritation. May cause asthmatic attacks due to allergic sensitization of the respiratory tract. Methemoglobinemia is characterized by dizziness, drowsiness, headache, shortness of breath, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), rapid heart rate and chocolate-brown blood. May cause nausea and possible vomiting.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause allergic respiratory reaction (asthma).

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors or dust may form explosive mixture with air.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Do not flush into a sewer. Avoid generating dusty conditions.

Section 7 - HANDLING and STORAGE
  Handling:
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 100-02-7: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystals
Color: brown - yellow
Odor: phenol-like
pH: 4.4(5g/l aq.sol.)
Vapor Pressure: Not available.
Viscosity: 2.56mPa.s@121 deg C
Boiling Point: 279 deg C @ 760mmHg (dec)
Freezing/Melting Point: > 112 deg C
Autoignition Temperature: 283 deg C ( 541.40 deg F)
Flash Point: 169 deg C ( 336.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 279 deg C
Solubility in water: 1.6 g/100 ml in water (25C)
Specific Gravity/Density:
Molecular Formula: C6H5NO3
Molecular Weight: 139.11

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, light, temperatures above 75C (167F), heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, caustic alkalis, combustible materials.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic gases, carbon dioxide, phenol.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 100-02-7: SM2275000 LD50/LC50:
CAS# 100-02-7: Dermal, guinea pig: LD50 = >1 gm/kg; Oral, mouse: LD50 = 282 mg/kg; Oral, rat: LD50 = 202 mg/kg; Skin, rat: LD50 = 1024 mg/kg.
Carcinogenicity:
4-Nitrophenol - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: LC50 = 37 mg/L; 30 min.; Microtox testDaphnia: Daphnia: LC50 = 37 mg/L; 24H; .Daphnia: Daphnia: LC50 = 37 mg/L; 24H; .log POW = 1.87

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: NITROPHENOLS
Hazard Class: 6.1
UN Number: 1663
Packing Group: III
IMO
Shipping Name: NITROPHENOLS
Hazard Class: 6.1
UN Number: 1663
Packing Group: III
RID/ADR
Shipping Name: NITROPHENOLS
Hazard Class: 6.1
UN Number: 1663
Packing group: III
USA RQ: CAS# 100-02-7: 100 lb final RQ (Listed under Nitrophenol, mixed); 45.4 k

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 100-02-7: 2
Canada
CAS# 100-02-7 is listed on Canada's DSL List.
CAS# 100-02-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-02-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Spectrum
NMR Spectrum 1H NMR : 400 MHz in DMSO-d6
expand collapse
IR Spectrum IR : nujol mull
expand collapse
Mass Spectrum Mass spectrum (electron ionization)
expand collapse
Raman Spectrum Raman : 4880 A,200 M,powder
expand collapse
ESR Spectrum ESR : ANION RADICAL, ELECTROLYTIC GENERATION
expand collapse
UV Spectrum UV/Visible spectrum
expand collapse
Toxicity
MUTATION DATA
expand collapse
Type of Test
DNA adduct
Exposure Route
Species Observed
Dose/Duration
50 umol/L
Toxic Effects
--
Reference
Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 89,95,1981
MUTATION DATA
expand collapse
Type of Test
DNA repair
Exposure Route
Species Observed
Dose/Duration
500 ug/disc
Toxic Effects
--
Reference
Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 170,11,1986
MUTATION DATA
expand collapse
Type of Test
DNA repair
Exposure Route
Species Observed
Dose/Duration
10 mg/plate
Toxic Effects
--
Reference
Biologisches Zentralblatt. (VEB Georg Thieme, Postfach 946, Leipzig DDR-7010, Ger. Dem. Rep.) V.1- 1881- Volume(issue)/page/year: 95,463,1976

Related Compound Information

PRODUCTS
Coming Soon
SUPPLIERS
Coming Soon
BRANDING
Coming Soon