tetrachloromethane

CAS No. 56-23-5

Formula: CCl4
Basic Info

Carbon Tetrachloride is used in biological studies to evaluate the genotoxicity and toxicity in primary hepatocyte culture of humans and lab animals.

Formula
CCl4
Molecular Weight
153.823
Exact Mass
151.875
LogP
2.5529
PSA
0
Synonyms

carbon chloride

tert-BuOCOCH3

1,1-dimethylethyl acetate

t-Butyl acetate

Acetic acid,1,1-dimethylethyl ester

acetic acid tert-butyl ester

carbone tetrachloride

anhydrous tetra-chloro-methane

Methane, tetrachloro-

Carbon tetrachloride

1,1-Dimethyl acetate

anhydrous tert-butyl acetate

tert-Butyl ethanoate

Texaco lead appreciator

tetrachloro-methane

tert-butyl N-acetate

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Properties
Appearance & Physical State
clear colorless liquid
Density
1.594
Boiling Point
76ºC
Melting Point
-23ºC
Flash Point
Use any means suitable for fire extinguisher
Refractive Index
1.459-1.46
Water Solubility
0.8 g/L (20 ºC)
Storage Condition
2-8ºC
Vapor Density
5.32 (vs air)
Vapor Pressure
4.05 psi ( 20 °C)
Safety Info
RTECS
FG4900000
Safety Statements
S23-S36/37-S45-S59-S61
WGK Germany
3
Risk Statements
R23/24/25; R40; R48/23; R52/53; R59
HS Code
2903140090
RIDADR
UN 1846
Hazard Class
6.1(a)
Packing Group
II
Hazard Codes
MSDS
SDS 1.0
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SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name tetrachloromethane

1.2 Other means of identification

Product number -
Other names tert-butyl N-acetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Volatile organic compounds
Uses advised against no data available

1.4 Supplier's details

Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
Xuhui District, Shanghai, China
Telephone +86(21)64956998
Fax +86(21)54365166

1.5 Emergency phone number

Emergency phone number +86-400-6021-666
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Acute toxicity - Oral, Category 3

Acute toxicity - Dermal, Category 3

Acute toxicity - Inhalation, Category 3

Carcinogenicity, Category 2

Specific target organ toxicity – repeated exposure, Category 1

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 3

Hazardous to the ozone layer, Category 1

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Danger

Hazard statement(s)

H301 Toxic if swallowed

H311 Toxic in contact with skin

H331 Toxic if inhaled

H351 Suspected of causing cancer

H372 Causes damage to organs through prolonged or repeated exposure

H412 Harmful to aquatic life with long lasting effects

H420 Harms public health and the environment by destroying ozone in the upper atmosphere

Precautionary statement(s)
Prevention

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P273 Avoid release to the environment.

Response

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/…

P321 Specific treatment (see ... on this label).

P330 Rinse mouth.

P302+P352 IF ON SKIN: Wash with plenty of water/...

P312 Call a POISON CENTER/doctor/…if you feel unwell.

P361+P364 Take off immediately all contaminated clothing and wash it before reuse.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P311 Call a POISON CENTER/doctor/…

P308+P313 IF exposed or concerned: Get medical advice/ attention.

P314 Get medical advice/attention if you feel unwell.

Storage

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 Dispose of contents/container to ...

P502 Refer to manufacturer or supplier for information on recovery or recycling

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
tetrachloromethane tetrachloromethane 56-23-5 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.

In case of skin contact

Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .

In case of eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

If swallowed

Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .

4.2 Most important symptoms/effects, acute and delayed

Dizziness, incoordination, anesthesia; may be accompanied by nausea and liver damage. Kidney damage also occurs, often producing decrease or stopping of urinary output. (USCG, 1999)

4.3 Indication of immediate medical attention and special treatment needed, if necessary

Irrigate eyes with water. Wash contaminated areas of body with soap and water. Gastric lavage, if swallowed, followed by saline catharsis. Oxygen and artificial respiration.

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

When fighting a fire in which carbon tetrachloride is involved, wear self-contained breathing apparatus.

5.2 Specific hazards arising from the chemical

Special Hazards of Combustion Products: Forms poisonous phosgene gas when exposed to open flames. Behavior in Fire: Decomposes to form chlorine and phosgene (USCG, 1999)

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in covered containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

6.3 Methods and materials for containment and cleaning up

1. VENTILATE AREA OF SPILL OR LEAK. 2. COLLECT FOR RECLAMATION OR ABSORB IN VERMICULITE, DRY SAND, EARTH, OR A SIMILAR MATERIAL.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Separated from food and feedstuffs and metals. See Chemical Dangers. Ventilation along the floor. Cool.Store in a cool, dry, well-ventilated location. Separate from alkali metals.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

Recommended Exposure Limit: 60 Min Short-Term Exposure Limit: 2 ppm, 12.6 mg/cu m

NIOSH has recommended that carbon tetrachloride be treated as a potential human carcinogen.

NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concn.

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state clear colorless liquid
Colour Colorless, clear, heavy liquid
Odour SWEETISH, AROMATIC, MODERATELY STRONG ETHEREAL; SOMEWHAT RESEMBLING THAT OF CHLOROFORM
Melting point/ freezing point -23ºC
Boiling point or initial boiling point and boiling range 76ºC
Flammability Noncombustible LiquidNot combustible. Gives off irritating or toxic fumes (or gases) in a fire.
Lower and upper explosion limit / flammability limit no data available
Flash point Use any means suitable for fire extinguisher
Auto-ignition temperature Not flammable (USCG, 1999)
Decomposition temperature no data available
pH no data available
Kinematic viscosity 2.03X10-3 Pa.s @ 250.00 K
Solubility In water:0.8 g/L (20 ºC)
Partition coefficient n-octanol/water (log value) log Kow= 2.83
Vapour pressure 4.05 psi ( 20 °C)
Density and/or relative density 1.594
Relative vapour density 5.32 (vs air)
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

... Generally inert ...

10.3 Possibility of hazardous reactions

Not flammableThe vapour is heavier than air.CARBON TETRACHLORIDE is a commonly used liquid in fire extinguishers to combat small fires. It has no flash point, it is not flammable. However, when heated to decomposition, it will emit fumes of extremely toxic phosgene and of hydrogen chloride. Forms explosive mixtures with chlorine trifluoride, calcium hypochlorite, decaborane, dinitrogen tetraoxide, fluorine. Forms impact-sensitive explosive mixtures with particles of many metals: lithium, sodium, potassium, beryllium, zinc, aluminum, barium. Vigorous exothermic reaction with allyl alcohol, boron trifluoride, diborane, disilane, aluminum chloride, dibenzoyl peroxide, potassium tert-butoxide, liquid oxygen, zirconium. [Bretherick, 5th ed., 1995, p. 666]. Potentially dangerous reaction with dimethylformamide or dimethylacetamide in presence of iron [Cardillo, P. et al., Ann. Chim. (Rome), 1984, 74, p. 129].

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

A paste of zinc powder and carbon tetrachloride (with kieselguhr as thickener) will readily burn after ignition by a high-temperature primer.

10.6 Hazardous decomposition products

Decomposes to form chlorine and phosgene.

11.Toxicological information

Acute toxicity

  • Oral: LD50 Rat oral 2920 mg/kg
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

NTP: Reasonably anticipated to be a human carcinogen

Reproductive toxicity

No information is available on the reproductive effects of carbon tetrachloride in humans. Limited epidemiological data have indicated a possible association between certain birth outcomes (e.g., birth weight, cleft palate) and drinking water exposure. However, as the water contained multiple chemicals, the role of carbon tetrachloride is unclear. Decreased fertility and degenerative changes in the testes have been observed in animals exposed to carbon tetrachloride by inhalation. Birth defects have not been observed in animals exposed to carbon tetrachloride by inhalation or ingestion.

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: LC50 Lepomis macrochirus (Bluegill) 125,000 ug/l/96 hr (static unmeasured)
  • Toxicity to daphnia and other aquatic invertebrates: no data available
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

AEROBIC: The static screening flask test method measured >87% degradation of carbon tetrachloride in 7 days in the original test, and 100% degradation in the second, third, and fourth trials(1). In a standard dilution test, 0% Theoretical BOD for carbon tetrachloride was measured(2).

12.3 Bioaccumulative potential

A BCF of 3.2-7.4 for carbon tetrachloride was measured(1). A measured BCF value for trout, rainbow trout and bluegill sunfish was found to be 17.37(2,3), 52.48(5), and 30.2(4) and 26.3(5), respectively. According to a classification scheme(6), these BCF values suggest the potential for bioconcentration in aquatic organisms is low.

12.4 Mobility in soil

The Koc for carbon tetrachloride was measured to be 71(1). According to a classification scheme(4), this Koc value suggests that carbon tetrachloride is expected to have high mobility in soil. Estimated retardation factor in breakthrough sampling in groundwater - 1.44-1.8(2,3).

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN1846 IMDG: UN1846 IATA: UN1846

14.2 UN Proper Shipping Name

ADR/RID: CARBON TETRACHLORIDE
IMDG: CARBON TETRACHLORIDE
IATA: CARBON TETRACHLORIDE

14.3 Transport hazard class(es)

ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1

14.4 Packing group, if applicable

ADR/RID: II IMDG: II IATA: II

14.5 Environmental hazards

ADR/RID: no IMDG: no IATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
tetrachloromethane tetrachloromethane 56-23-5 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
EC Inventory Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
Vietnam National Chemical Inventory Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 17, 2017
Revision Date Aug 17, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
MSDS
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Name: Carbon Tetrachloride, 99+%, Spectrophotometric Grade Material Safety Data Sheet
Synonym: Tetrachloromethane; Carbon tet; Carbona; Carbon chloride; Methane tetrachloride.
CAS: 56-23-5
Section 1 - Chemical Product MSDS Name: Carbon Tetrachloride, 99+%, Spectrophotometric Grade Material Safety Data Sheet
Synonym: Tetrachloromethane; Carbon tet; Carbona; Carbon chloride; Methane tetrachloride.
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
56-23-5 Carbon Tetrachloride >99 200-262-8
Hazard Symbols: T N
Risk Phrases: 23/24/25 40 59 48/23 52/53
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Toxic by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Dangerous for the ozone layer.
Toxic : danger of serious damage to health by prolonged exposure through inhalation. Harmful to aquatic organisms; may cause long-term adverse effects in the aquatic environment.Cancer suspect agent. Potential Health Effects
Eye:
Causes eye irritation. Vapors cause eye irritation.
Skin:
Causes skin irritation. May be absorbed through the skin in harmful amounts. Contact with the skin defats the skin.
Ingestion:
May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Substance is a hepatotoxin and is capable of producing a toxic effect on the liver.
Inhalation:
May cause liver and kidney damage. Exposure produces central nervous system depression. May be harmful if inhaled.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic ingestion may cause effects similar to those of acute ingestion. May cause liver and kidney damage. May cause cancer according to animal studies. Chronic exposure may cause visual disturbances. Carbon tetrachloride is a CNS depressant.
SECTION 4 - FIRST AID MEASURES
Eyes:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Wash clothing before reuse.
Ingestion:
Potential for aspiration if swallowed. Get medical aid immediately. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.
Inhalation:
Poison material. If inhaled, get medical aid immediately. Remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:


SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Material will not burn. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Isolate area and deny entry. Provide ventilation.
SECTION 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Do not breathe vapor. Use only with adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Use only under a chemical fume hood. Personal Protective Equipment
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear, colorless
Odor: chloroform-like
pH: Not available.
Vapor Pressure: 91 mm Hg @ 20 deg C
Viscosity: 0.97 PAS 20 deg C
Boiling Point: 76 deg C @ 760 mm Hg
Freezing/Melting Point: -23 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >100 deg C
Solubility in water: Insoluble.
Specific Gravity/Density: 1.5900 g/cm3
Molecular Formula: CCl4
Molecular Weight: 153.82
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Light, excess heat.
Incompatibilities with Other Materials:
Alkali metals, powdered aluminum, powdered magnesium, zinc powder, ethylene, allyl alcohol, barium, fluorine, dimethylformamide, powered beryllium, decaborane, potassium tert-butoxide.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, phosgene, carbon monoxide, carbon dioxide, chlorine dioxide, which may be spontaneously explosive.
Hazardous Polymerization: Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 56-23-5: FG4900000
LD50/LC50:
CAS# 56-23-5: Dermal, guinea pig: LD50 = >9400 uL/kg; Draize test,
rabbit, eye: 2200 ug/30S Mild; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 4 mg Mild; Draize test, rabbit,
skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 9526 ppm/8H;
Inhalation, rat: LC50 = 8000 ppm/4H; Oral, mouse: LD50 = 8263 mg/kg;
Oral, rabbit: LD50 = 5760 mg/kg; Oral, rat: LD50 = 2350 mg/kg; Skin,
rabbit: LD50 = >20 gm/kg; Skin, rat: LD50 = 5070 mg/kg.
Carcinogenicity:
Carbon Tetrachloride - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 20.8-41.4 mg/L; 96 Hr.; Flow-through; 21.7 degrees CFish: Bluegill/Sunfish: LC50 = 27-125 mg/L; 96 Hr.; Static Conditions; 23 degrees CBacteria: Phytobacterium phosphoreum: EC50 = 6.0 mg/L; Not available; Microtox testBacteria: Phytobacterium
phosphoreum: EC50 = 33.0 mg/L; 30 minutes; Microtox test
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA
Shipping Name: CARBON TETRACHLORIDE
Hazard Class: 6.1
UN Number: 1846
Packing Group: II IMO
Shipping Name: CARBON TETRACHLORIDE
Hazard Class: 6.1
UN Number: 1846
Packing Group: II RID/ADR
Shipping Name: CARBON TETRACHLORIDE
Hazard Class: 6.1
UN Number: 1846
Packing group: II
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R 40 Limited evidence of a carcinogenic effect. R 59 Dangerous for the ozone layer.
R 48/23 Toxic : danger of serious damage to health by prolonged exposure through inhalation. R 52/53 Harmful to aquatic organisms; may cause long-term adverse effects in the aquatic environment.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray. S 36/37 Wear suitable protective clothing and gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 59 Refer to manufacturer/supplier for information on recovery/recycling. S 61 Avoid release to the environment. Refer to special instructions/Safety data sheets. WGK (Water Danger/Protection) CAS# 56-23-5: 3 United Kingdom Occupational Exposure Limits United Kingdom Maximum Exposure Limits Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 56-23-5 is not listed on Canada's Ingredient Disclosure List. Exposure Limits CAS# 56-23-5: OEL-ARAB Republic of Egypt:TWA 5 ppm (30 mg/m3);Skin OEL-AUSTRALIA:TWA 5 ppm (30 mg/m3);Skin;Carcinoge OEL-BELGIUM:TWA 5 ppm (31 mg/m3);Skin;Carcinogen OEL-CZECHOSLOVAKIA:TWA 10 mg/m3;STEL 20 mg/m3 OEL-DENMARK:TWA 2 ppm (13 mg/m3);Skin OEL-FINLAND:TWA 5 ppm (31 mg/m3);STEL 10 ppm (63 mg/m3);Skin;CAR OEL-FRANCE:TWA 2 ppm (12 mg/m3);STEL 10 ppm (60 mg/m3) OEL-GERMANY:TWA 10 ppm (65 mg/m3);Skin;Carcinogen OEL-HUNGARY:STEL 10 mg/m3;Skin;Carcinogen OEL-INDIA:TWA 5 ppm (30 mg/m3);Skin;Carcinogen OEL-JAPAN:TWA 10 ppm (63 mg/m3);Skin;Carcinogen OEL-THE NETHERLANDS:TWA 2 ppm (12.6 mg/m3);Skin OEL-THE PHILIPPINES:TWA 10 ppm (65 mg/m3);Skin OEL-POLAND:TWA 20 mg/m3 OEL-RUSSIA:TWA 10 ppm;STEL 20 mg/m3 OEL-SWEDEN:TWA 2 ppm (13 mg/m3);STEL 3 ppm (19 mg/m3);Skin;CAR OEL-SWITZERLAND:TWA 5 ppm (30 mg/m3);STEL 10 ppm (60 mg/m3);Skin OEL-THAILAND:TWA 10 ppm;STEL 25 ppm OEL-UNITED KINGDOM:TWA 10 ppm (65 mg/m3);STEL 20 ppm;Skin OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV US FEDERAL TSCA CAS# 56-23-5 is not listed on the TSCA inventory. It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 7/20/1999 Revision #4 Date: 11/06/2002 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A
Spectrum
NMR Spectrum 13C NMR : in CDCl3
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IR Spectrum IR : liquid film
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Mass Spectrum Mass
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Raman Spectrum Raman : 4880 A,100M,liquid
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ESR Spectrum ESR : PHOTOLYSIS OF (CH3)3SIH/DTBPO IN CCL4
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