Isopropyl ether

CAS No. 108-20-3

Formula: C6H14O
Basic Info

Diisopropyl ether is secondary ether that is used as a solvent. It is a colorless liquid that is slightly soluble in water, but miscible with organic solvents. It is used as an extractant and an oxygenate gasoline additive. It is obtained industrially as a byproduct in the production of isopropanol by hydration of propene. Diisopropyl ether is sometimes represented by the abbreviation "DIPE".

Molecular Weight
Exact Mass

Propane, 2,2‘-oxybis-


Isopropyl oxide



Isoprpyl ether

Diisoproyl ether

i-propyl ether

Diisopropyl Ether




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Appearance & Physical State
colourless liquid
Boiling Point
Melting Point
Flash Point
Refractive Index
Water Solubility
9 g/L (20 ºC)
Stability Extremely flammable. This material is a serious fire and explosion risk. Vapour may travel considerable distances to an ignition source, which need not be an open flame, but may be a hot plate, steam pipe, etc. Vapour may be ignited by the static
Storage Condition
Flammables area
Vapor Density
3.5 (vs air)
Vapor Pressure
120 mm Hg ( 20 °C)
Safety Info
Safety Statements
WGK Germany
Risk Statements
R11; R19; R66; R67
HS Code
UN 1159 3/PG 2
Hazard Class
Packing Group
Caution Statement
P210; P370 + P378; P403 + P235
Hazard Codes
Hazard Declaration
SDS 1.0
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According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017


1.1 GHS Product identifier

Product name Isopropyl ether

1.2 Other means of identification

Product number -
Other names izopropylowyeter

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food Additives: EXTRACTION_SOLVENT
Uses advised against no data available

1.4 Supplier's details

Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
Xuhui District, Shanghai, China
Telephone +86(21)64956998
Fax +86(21)54365166

1.5 Emergency phone number

Emergency phone number +86-400-6021-666
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Flammable liquids, Category 2

Specific target organ toxicity – single exposure, Category 3

2.2 GHS label elements, including precautionary statements

Signal word


Hazard statement(s)

H225 Highly flammable liquid and vapour

H336 May cause drowsiness or dizziness

Precautionary statement(s)

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P233 Keep container tightly closed.

P240 Ground and bond container and receiving equipment.

P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.

P242 Use non-sparking tools.

P243 Take action to prevent static discharges.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.


P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P370+P378 In case of fire: Use ... to extinguish.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P312 Call a POISON CENTER/doctor/…if you feel unwell.


P403+P235 Store in a well-ventilated place. Keep cool.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.


P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification


3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
Isopropyl ether Isopropyl ether 108-20-3 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

Fresh air, rest. Refer for medical attention.

In case of skin contact

Remove contaminated clothes. Rinse skin with plenty of water or shower.

In case of eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

If swallowed

Rinse mouth. Rest. Refer for medical attention .

4.2 Most important symptoms/effects, acute and delayed

Inhalation causes anesthesia, nausea, headache, dizziness, and irritation of the eyes and nose. Contact of liquid with eyes causes only minor injury; repeated contact with skin will remove natural oils and may cause dermatitis. (USCG, 1999)

4.3 Indication of immediate medical attention and special treatment needed, if necessary

Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Provide a low-stimulus environment. Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Treat frostbite by rapid rewarming ... . /Ethers and related compounds/

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Alcohol foam, CO2, foam, dry chemical.

5.2 Specific hazards arising from the chemical

Behavior in Fire: Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash back. Containers may explode when heated. (USCG, 1999)

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Evacuate danger area! Consult an expert! Personal protection: self-contained breathing apparatus. Ventilation. Collect leaking and spilled liquid in sealable metal containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.

6.3 Methods and materials for containment and cleaning up

1. Remove all ignition sources. 2. Ventilate area of spill or leak. 3. For small quantities, absorb on paper towels. Evaporate in a safe place (such as fume hood). Allow sufficient time for evaporating vapors to completely clear the hood ductwork. Burn the paper in a suitable location away from combustible materials. Large quantities can be reclaimed or collected and atomized in a suitable combustion chamber.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Fireproof. Cool. Keep in the dark. Keep in a well-ventilated room. Store only if stabilized.Store in cool, dry, well-ventilated location. Separate from acids & oxidizing materials.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 500 ppm (2100 mg/cu m).

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state colourless liquid
Colour Colorless volatile liquid
Odour Sweet, slightly sharp, pungent like camphor and ethyl ether
Melting point/ freezing point -85.5ºC
Boiling point or initial boiling point and boiling range 68-69°C(lit.)
Flammability Class IB Flammable Liquid: Fl.P. below 22.78°C and BP at or above 37.78°C.Highly flammable.
Lower and upper explosion limit / flammability limit LOWER 1.4%, UPPER 7.9%
Flash point -29°C
Auto-ignition temperature 441.67°C
Decomposition temperature no data available
pH no data available
Kinematic viscosity 0.273 centipoise at 20 deg F
Solubility In water:9 g/L (20 ºC)
Partition coefficient n-octanol/water (log value) log Kow= 1.52
Vapour pressure 120 mm Hg ( 20 °C)
Density and/or relative density 0.725g/mLat 25°C(lit.)
Relative vapour density 3.5 (vs air)
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Keeping ethers from becoming anhydrous plus the addition of antioxidants will help reduce this explosion hazard.

10.3 Possibility of hazardous reactions

FLAMMABLE LIQUID.The vapour is heavier than air and may travel along the ground; distant ignition possible. As a result of flow, agitation, etc., electrostatic charges can be generated.Ethers, such as DIISOPROPYL ETHER, can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert. Mixing diisopropyl ether in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid, nitric acid, [NFPA 1991].

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

Mixing diisopropyl ether and chlorosulfonic acid in a closed container caused the temp and pressure to incr. Mixing diisopropyl ether and 70% nitric acid in a closed container caused the temp and pressure to increase.

10.6 Hazardous decomposition products

When heated to decomposition it emits acrid smoke and fumes.

11.Toxicological information

Acute toxicity

  • Oral: no data available
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available


no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: LC50 Pimephales promelas (fathead minnow) 91.7 mg/l 96 hr flow-through bioassay, wt 0.12 g, water hardness 45.5 mg/l CaCO3, temp: 25 + or - 1°C, pH 7.5, dissolved oxygen greater than 60% of saturation
  • Toxicity to daphnia and other aquatic invertebrates: no data available
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

No data concerning the biodegradation of isopropyl ether in environmental media were located. An activated sludge aqueous screening study found that the compound was biodegraded slowly after a 15 day lag period with a 25% theoretical biological oxygen demand being measured after 25 days incubation(1). A screening test study utilizing a sewage inoculum also indicated slow biodegradation as indicated by the 7% theoretical biological oxygen demand which was measured after 5 days(2). These screening test results suggest that isopropyl ether may be resistent to biodegradation in the environment(SRC). Many ethers are known to be resistant to biodegradation(3).

12.3 Bioaccumulative potential

An estimated BCF of 8 was calculated for isopropyl ether(SRC), using a log Kow of 1.52(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

12.4 Mobility in soil

The Koc of isopropyl ether is estimated as approximately 160(SRC), using a log Kow of 1.52(1) and a regression-derived equation(2,SRC). According to a classification scheme(3), this estimated Koc value suggests that isopropyl ether is expected to have high mobility in soil(SRC).

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods


The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN1159 IMDG: UN1159 IATA: UN1159

14.2 UN Proper Shipping Name


14.3 Transport hazard class(es)


14.4 Packing group, if applicable


14.5 Environmental hazards

ADR/RID: no IMDG: no IATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
Isopropyl ether Isopropyl ether 108-20-3 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
EC Inventory Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
Vietnam National Chemical Inventory Not Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 12, 2017
Revision Date Aug 12, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%


  • IPCS - The International Chemical Safety Cards (ICSC), website:
  • HSDB - Hazardous Substances Data Bank, website:
  • IARC - International Agency for Research on Cancer, website:
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website:
  • CAMEO Chemicals, website:
  • ChemIDplus, website:
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website:
  • Germany GESTIS-database on hazard substance, website:
  • ECHA - European Chemicals Agency, website:

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
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Name: Isopropyl Ether Material Safety Data Sheet
Synonym: Diisopropyl ether; DIPE; 2-Isopropoxypropane
CAS: 108-20-3
Section 1 - Chemical Product   MSDS Name:Isopropyl Ether Material Safety Data Sheet
Synonym:Diisopropyl ether; DIPE; 2-Isopropoxypropane

CAS# Chemical Name content EINECS#
108-20-3 Isopropyl ether 98 203-560-6
Hazard Symbols: F
Risk Phrases: 11 19 66 67

Highly flammable. May form explosive peroxides. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness.Air sensitive.
Potential Health Effects
Causes mild eye irritation.
May cause skin irritation. Excessive drying of the skin may result from repeated or prolonged contact.
Aspiration hazard. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal.
May cause respiratory tract irritation. May cause narcotic effects in high concentration. May cause drowsiness, unconsciousness, and central nervous system depression.
Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation may cause effects similar to those of acute inhalation.

  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Get medical aid if irritation develops or persists. Wash clothing before reuse. Rinse area with large amounts of water for at least 15 minutes.
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

  General Information:
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Forms peroxides of unknown stability. Extremely flammable liquid and vapor. Vapor may cause flash fire. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

  General Information: Use proper personal protective equipment as indicated in Section 8.
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.

Section 7 - HANDLING and STORAGE
Wash thoroughly after handling. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Loosen closure cautiously before opening. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. If peroxide formation is suspected, do not open or move container. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Avoid breathing vapor.
Keep away from sources of ignition. Store in a tightly closed container. Keep under a nitrogen blanket. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from strong acids. Store protected from light. Containers should be dated when opened and tested periodically for the presence of peroxides. Test for peroxide levels in unpreserved product upon expiration. Products with excessive peroxide must be disposed of promptly and properly.

  Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 108-20-3: United Kingdom, WEL - TWA: 250 ppm TWA; 1060 mg/m3 TWA United Kingdom, WEL - STEL: 310 ppm STEL; 1310 mg/m3 STEL United States OSHA: 500 ppm TWA; 2100 mg/m3 TWA Belgium - TWA: 250 ppm VLE; 1055 mg/m3 VLE Belgium - STEL: 310 ppm VLE; 1319 mg/m3 VLE France - VME: 250 ppm VME; 1050 mg/m3 VME Germany: 200 ppm TWA; 850 mg/m3 TWA Malaysia: 250 ppm TWA; 1040 mg/m3 TWA Netherlands: 250 ppm MAC; 1050 mg/m3 MAC Russia: 4 mg/m3 TWA Spain: 250 ppm VLA-ED; 1060 mg/m3 VLA-ED Spain: 310 ppm VLA-EC; 1310 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Physical State: Liquid
Color: clear, colorless
Odor: Ethereal odor
pH: Not available.
Vapor Pressure: 150 mm Hg @ 25 deg C
Viscosity: 0.38 mPas 25 deg C
Boiling Point: 68 deg C @ 760 mm Hg
Freezing/Melting Point: 0 deg C
Autoignition Temperature: 443 deg C ( 829.40 deg F)
Flash Point: -29 deg C ( -20.20 deg F)
Explosion Limits, lower: 1.10 vol %
Explosion Limits, upper: 21.00 vol %
Decomposition Temperature:
Solubility in water: 0.9 G/100ML (20C)
Specific Gravity/Density: .7250 g/ml
Molecular Formula: C6H14O
Molecular Weight: 102.18

  Chemical Stability:
Peroxide formation may occur in containers that have been opened and remain in storage.
Conditions to Avoid:
Light, ignition sources, exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents, chlorosulfonic acid, nitric acid, propionyl chloride.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, peroxides.
Hazardous Polymerization: Has not been reported.

CAS# 108-20-3: TZ5425000 LD50/LC50:
CAS# 108-20-3: Inhalation, mouse: LC50 = 131 gm/m3; Inhalation, mouse: LC50 = 130800 mg/m3; Inhalation, rabbit: LC50 = 121 gm/m3; Inhalation, rabbit: LC50 = 120600 mg/m3; Inhalation, rat: LC50 = 162 gm/m3; Inhalation, rat: LC50 = 161700 mg/m3; Oral, mouse: LD50 = 3600 mg/kg; Oral, rat: LD50 = 5880 mg/kg; Skin, rabbit: LD50 = 20 mL/kg.
Isopropyl ether - Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.

Fish: Fathead Minnow: LC50 = 91.7 mg/L; 96 Hr.; Flow-throughFish: Bluegill/Sunfish: LC50 = 6600-7000 mg/L; 96 Hr.; UnspecifiedFish: Goldfish: LC50 = 380 mg/L; 24 Hr.; Modified ASTMD1345Bacteria: Phytobacterium phosphoreum: EC50 = 500 mg/L; 5 Minutes; Microtox testWater danger/protection: WGK 1 Fathead minnow (Pimephales promelas) LC50: 91.7 mg/l/96hr

  Dispose of in a manner consistent with federal, state, and local regulations.

Hazard Class: 3
UN Number: 1159
Packing Group: II
Hazard Class: 3.1
UN Number: 1159
Packing Group: II
Hazard Class: 3
UN Number: 1159
Packing group: II

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
R 19 May form explosive peroxides.
R 66 Repeated exposure may cause skin dryness or
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
WGK (Water Danger/Protection)
CAS# 108-20-3: 1
CAS# 108-20-3 is listed on Canada's DSL List.
CAS# 108-20-3 is listed on Canada's Ingredient Disclosure List.
CAS# 108-20-3 is listed on the TSCA inventory.

NMR Spectrum 1H NMR : parameter in CDCl3
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IR Spectrum IR : liquid film
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Mass Spectrum Mass spectrum (electron ionization)
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Raman Spectrum Raman : 4880 A,100M,liquid
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