(E)-1,3-dichloropropene

CAS No. 10061-02-6

Formula: C3H4Cl2
Basic Info

trans-1,3-Dichloropropene is used in a biological study to evaluate the fumigant emission and distribution in relation to soil moisture and texture.

Formula
C3H4Cl2
Molecular Weight
110.97
Exact Mass
109.969
LogP
1.9777
PSA
0
Synonyms

1-Propene, 1,3-dichloro-, (E)-

Trans-1,3-Dichloropropene

(E)-1,3-dichloroprop-1-ene

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Properties
Appearance & Physical State
A clear colorless liquid with chloroform odor.
Density
1.21
Boiling Point
112ºC
Melting Point
-95ºC
Flash Point
27ºC
Refractive Index
n20/D 1.472(lit.)
Stability
Stable. Flammable. Incompatible with strong oxidizing agents, aluminium, aluminium alloys, some metal salts and halogens. May be light sensitive.
Storage Condition
0-6ºC
Safety Info
Safety Statements
S16-S36/37
Risk Statements
R10; R22; R40
RIDADR
UN 2047
Hazard Class
3.2
Packing Group
III
Hazard Codes
MSDS
SDS 1.0
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SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name (E)-1,3-dichloropropene

1.2 Other means of identification

Product number -
Other names 1-Propene, 1,3-dichloro-, (E)-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. 1,3-Dichloropropene is the predominant component of several formulations used in agriculture as soil fumigants for parasitic nematodes.
Uses advised against no data available

1.4 Supplier's details

Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
Xuhui District, Shanghai, China
Telephone +86(21)64956998
Fax +86(21)54365166

1.5 Emergency phone number

Emergency phone number +86-400-6021-666
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Flammable liquids, Category 3

Skin irritation, Category 2

Eye irritation, Category 2

Specific target organ toxicity – single exposure, Category 3

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Warning

Hazard statement(s)

H226 Flammable liquid and vapour

H315 Causes skin irritation

H319 Causes serious eye irritation

H335 May cause respiratory irritation

Precautionary statement(s)
Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P233 Keep container tightly closed.

P240 Ground and bond container and receiving equipment.

P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.

P242 Use non-sparking tools.

P243 Take action to prevent static discharges.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P264 Wash ... thoroughly after handling.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

Response

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P370+P378 In case of fire: Use ... to extinguish.

P302+P352 IF ON SKIN: Wash with plenty of water/...

P321 Specific treatment (see ... on this label).

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P312 Call a POISON CENTER/doctor/…if you feel unwell.

Storage

P403+P235 Store in a well-ventilated place. Keep cool.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Disposal

P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
(E)-1,3-dichloropropene (E)-1,3-dichloropropene 10061-02-6 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

Fresh air, rest. Refer for medical attention.

In case of skin contact

Wear protective gloves when administering first aid. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .

In case of eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

If swallowed

Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting. Refer for medical attention .

4.2 Most important symptoms/effects, acute and delayed

VAPOR: Irritating to eyes, nose and throat. LIQUID: Will burn skin and eyes. Harmful if swallowed. (USCG, 1999)

SYMPTOMS: Symptoms of exposure to this compound may include local irritation of the eyes skin and respiratory tract, dermatitis, gasping, coughing, substernal pain, extreme respiratory distress, lacrimation, central nervous system depression, acute gastrointestinal distress with pulmonary congestion and edema. It may also cause injury to the liver, kidneys and heart. ACUTE/CHRONIC HAZARDS: This compound is irritating to the skin, eyes and mucous membranes. It may also cause lacrimation. When heated to decomposition it emits toxic fumes.

4.3 Indication of immediate medical attention and special treatment needed, if necessary

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. /Dichloropropenes/

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Specific hazards arising from the chemical

FLAMMABLE. POISONOUS GASES ARE PRODUCED IN FIRE. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Toxic and irritating gases may be generated. (USCG, 1999)

Flash point data for this chemical are not available, however literature indicates that this material is flammable.

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Ventilation. Remove all ignition sources. Personal protection: chemical protection suit including self-contained breathing apparatus. Collect leaking and spilled liquid in sealable plastic containers as far as possible. Do NOT let this chemical enter the environment.

6.3 Methods and materials for containment and cleaning up

ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Fireproof. Separated from metals and oxidants. Well closed. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature 2 - 8°C.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

NIOSH considers 1,3-dichloropropene to be a potential occupational carcinogen. NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration.

Recommended Exposure Limit: 10 Hour Time-Weighted Average: 1 ppm (5 mg/cu m), skin.

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state A clear colorless liquid with chloroform odor.
Colour Colorless to straw-colored liquid
Odour Pungent odor
Melting point/ freezing point 303°C(lit.)
Boiling point or initial boiling point and boiling range 112°C
Flammability Class IC Flammable Liquid: Fl.P. at or above 22.78°C and below 37.78°C.Flammable. Gives off irritating or toxic fumes (or gases) in a fire.
Lower and upper explosion limit / flammability limit Lower flammable limit: 5.3% by volume; Upper flammable limit: 14.5% by volume
Flash point 21°C(lit.)
Auto-ignition temperature no data available
Decomposition temperature no data available
pH no data available
Kinematic viscosity no data available
Solubility less than 0.1 mg/mL at 16.5°C
Partition coefficient n-octanol/water (log value) log Kow = 2.06 (cis-isomer), 2.03 (trans-isomer) at 25°C
Vapour pressure 27.9 mm Hg at 20°C ; 28 mm Hg at 25°C
Density and/or relative density 1.21
Relative vapour density 3.83 (Relative to Air)
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Flammable liquid.The vapour is heavier than air and may travel along the ground; distant ignition possible. As a result of flow, agitation, etc., electrostatic charges can be generated.1,3-DICHLOROPROPENE reacts vigorously with oxidizing materials. Reacts with aluminum, active metals, and halogenated compounds. Also reacts with acids and thiocyanates. Corrosive to magnesium, magnesium alloys and aluminum alloys. Incompatible with some metal salts .

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

Incompatible materials: Metals, strong oxidizing agents

10.6 Hazardous decomposition products

Hazardous decomposition products formed under fire conditions - Carbon oxides, hydrogen chloride gas

11.Toxicological information

Acute toxicity

  • Oral: LD50 Rat oral 140 + or - 25 mg/kg
  • Inhalation: LC50 F333 rat (female) inhalation 904 ppm (4104 mg/cu m)/4 hr
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

Evaluation: No epidemiological data relevant to the carcinogenicity of 1,3-dichloropropene were available. There is sufficient evidence in experimental animals for the carcinogenicity of mixed isomers of 1,3-dichloropropene (technical grade). Overall evaluation: 1,3-Dichloropropene (technical grade) is possibly carcinogenic to humans (Group 2B).

Reproductive toxicity

A study of male workers engaged in the manufacture of 1,3-dichloropropene indicated no significant effect on fertility at exposure levels occurring in the work environment. No evidence of developmental toxicity was observed in rats or rabbits exposed to 1,3-dichloropropene by inhalation, but significant maternal toxicity was seen in both species. In one study of rats exposed by inhalation, fewer fetuses per litter were reported at the highest exposure concentration but maternal toxicity was also observed. In other studies, no adverse reproductive effects were observed in rats and mice exposed by inhalation.

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: LC50; Species: Pimephales promelas (Fathead minnow) weight 0.9 g; Conditions: static bioassay without aeration, 18°C, pH 7.2-7.5, water hardness 40-50 mg/L CaCO3, alkalinity 30-35 mg/L; Concentration: 4100 ug/L for 96 hr (95% confidence limit: 3390-4970 ug/L) /Technical material, 100%
  • Toxicity to daphnia and other aquatic invertebrates: LC50; Species: Daphnia magna (Water flea) 1st instar; Conditions: static bioassay without aeration, 21°C, pH 7.2-7.5, water hardness 40-50 mg/L CaCO3, alkalinity 30-35 mg/L; Concentration: 90 ug/L for 48 hr (95% confidence limit: 63-129 ug/L) /Technical material, 100%
  • Toxicity to algae: EC50; Species: Anabaena flosaquae (Blue-Green Algae); Conditions: freshwater, static; Concentration: 108000 ug/L for 120 hr (95% confidence interval: 50000-232000 ug/L); Effect: decreased population abundance /96% purity
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

AEROBIC: 1,3-Dichloropropene, present at 100 mg/L, reached 3% of its theoretical BOD in 4 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test which classified the compound as not readily biodegradable(1); additional degradation was observed yielding 3-chloro-2-propen-1-ol(1), possibly from hydrolysis and degradation of the hydrolysis products(SRC). A BOD dilution water study using settled domestic wastewater as the microbia1 inoculum found that 5-10 mg/L concentrations of 1,3-dichloropropene were degraded by 54-85% after 7 days of incubation with the faster rates achieved following weekly adaptations(1); however, the rate of biodegradation for 1,3-dichloropropene in natural waters cannot be inferred from this screening study data(3). Common soil bacteria were able to utilize 1,3-dichloropropene as a sole carbon source in pure culture studies(4). Twelve weeks after labeled cis- or trans-1,3-dichloropropene was added to soil and stored in sealed containers, 19% of the cis and 18% of the trans isomers remained in sandy loam and 10% of cis and 22% of trans isomer remained in medium loam(5). After 20 weeks, 5% and 4% of the cis and trans isomer, respectively, remained in sandy loam and 3% and 14%, respectively remained in the medium loam(5); the half-life of the applied dichloropropenes were 3-4 weeks; it was possible that some of the parent compound was lost by volatilization(5). 14C-1,3-Dichloropropene, added at 100 ug/g soil and incubated aerobically in the dark at 25°C, displayed half-lives of 1.8, 12.3, and 61 days using Wahiawa silt clay, Catlin silt loam, and Fuquay loamy sand, respectively(6); degradation products were 3-chloroallyl alcohol, 3-chloroacrylic acid, numerous minor carboxylic acid metabolites, and carbon dioxide(6). Degradation of 1,3-dichloropropene was greatly enhanced in amended soils compared to the unamended soil, and the degree of acceleration varied with the type as well as the rate of amendment(7); compost manure was more effective in stimulating 1,3-dichloropropene degradation than a less decomposed biosolid-manure mix; the acceleration in compost manure-amended soils was a combined result of enhanced chemical and microbial degradation, since sterilization only partially reduced the enhanced degradation(7). Complete mineralization of 1,3-dichloropropene, based on chloride release, can be a matter of years(8). A 5 ug/mL test compound added to a sediment sample from a drainage ditch at an agricultural field station in Marcham, England was readily converted to 3-chloropropionic acid(9). 1,3-Dichloropropene is degraded more rapidly in soil that has a history of treatment with this pesticide than in previously untreated soil(3). While the degradation rates of the cis- and trans- isomers are similar in untreated soil, degradation in previously treated soil has been shown to be more rapid for trans-1,3-dichloropropene than for cis-1,3-dichloropropene(3).

12.3 Bioaccumulative potential

An estimated BCF of 10 was calculated in fish for 1,3-dichloropropene(SRC), using a log Kow of 2.04 (average for the cis- and trans-isomers)(1) and a regression-derived equation(2). According to a classification scheme(2), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

12.4 Mobility in soil

Measured Koc values of 23 and 26 for the cis- and trans- isomers of 1,3-dichloropropene, respectively, have been reported(1). The average Koc for 3 soils with organic carbon of 3.19%, 10.4%, and 55.1% was 27 and 28 for cis- and trans-1,3-dichloropropene, respectively(2). The average maximum Koc values were 20 for sand, 25 for loamy sand, and 41 and 42 for two clay soils(3). According to a classification scheme(4), these Koc values suggest that 1,3-dichloropropene is expected to have very high mobility in soil. The adsorption onto soil from the vapor is greater for the trans- than the cis- isomer(3). The adsorption isotherm for the vapor/soil system is linear(3). When 1,3-dichloropropene is used in farm fields, it is sprayed directly on the ground or injected into the soil(5). Once in the soil, it can exist as a gas or dissolved in water. 1,3-Dichloropropene can adsorb more strongly to soil when it is in the vapor phase than when it is dissolved in water(5). Vapor-phase adsorption can be approximately 3-times greater at 2°C than it is at 20°C, and adsorption isotherms measured for humus sand, peaty sand, and peat indicate vapor-phase Koc values ranging from 450 to 750(5). According to a classification scheme(4), these vapor-phase Koc values suggest that 1,3-dichloropropene may have moderate to low mobility in soil.

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN2047 IMDG: UN2047 IATA: UN2047

14.2 UN Proper Shipping Name

ADR/RID: DICHLOROPROPENES
IMDG: DICHLOROPROPENES
IATA: DICHLOROPROPENES

14.3 Transport hazard class(es)

ADR/RID: 3 IMDG: 3 IATA: 3

14.4 Packing group, if applicable

ADR/RID: II IMDG: II IATA: II

14.5 Environmental hazards

ADR/RID: no IMDG: no IATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
(E)-1,3-dichloropropene (E)-1,3-dichloropropene 10061-02-6 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Not Listed.
EC Inventory Not Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Not Listed.
New Zealand Inventory of Chemicals (NZIoC) Not Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Not Listed.
Vietnam National Chemical Inventory Not Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 10, 2017
Revision Date Aug 10, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
MSDS
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
  Product identifiers
    Product name        : trans-1,3-Dichloropropene    
    REACH No.        : A registration number is not available for this substance as the substance    
    or its uses are exempted from registration, the annual tonnage does not
    require a registration or the registration is envisaged for a later
    registration deadline.
    CAS-No.        : 10061-02-6    
  Relevant identified uses of the substance or mixture and uses advised against
    Identified uses        : Laboratory chemicals, Manufacture of substances    
  
  

SECTION 2: Hazards identification
  Classification of the substance or mixture
  Classification according to Regulation (EC) No 1272/2008
    Flammable liquids (Category 3), H226
    Eye irritation (Category 2), H319
    Specific target organ toxicity - single exposure (Category 3), H335
    Skin irritation (Category 2), H315
    Skin sensitisation (Category 1), H317
    Acute aquatic toxicity (Category 1), H400
    Chronic aquatic toxicity (Category 1), H410
    Acute toxicity, Dermal (Category 3), H311
    Acute toxicity, Oral (Category 3), H301
    Acute toxicity, Inhalation (Category 4), H332
    Aspiration hazard (Category 1), H304
    For the full text of the H-Statements mentioned in this Section, see Section 16.
  Classification according to EU Directives 67/548/EEC or 1999/45/EC
    T, N Toxic, Dangerous for the        R10, R20, R24/25, R36/37/38, R43, R65, R50/53    
    environment
    For the full text of the R-phrases mentioned in this Section, see Section 16.
  Label elements
  Labelling according Regulation (EC) No 1272/2008
    Pictogram
    Signal word        Danger    
    Hazard statement(s)
    H226        Flammable liquid and vapour.    
    H301        Toxic if swallowed.    
    H304        May be fatal if swallowed and enters airways.    
    H311        Toxic in contact with skin.    
    H315        Causes skin irritation.    
    H317        May cause an allergic skin reaction.    
    H319        Causes serious eye irritation.    
    H332        Harmful if inhaled.    
    H335        May cause respiratory irritation.    
    H410        Very toxic to aquatic life with long lasting effects.    
    Precautionary statement(s)
    P261        Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.    
    P273        Avoid release to the environment.    
    P280        Wear protective gloves/ protective clothing.    
    P301 + P310        IF SWALLOWED: Immediately call a POISON CENTER or doctor/    
    physician.
    P305 + P351 + P338        IF IN EYES: Rinse cautiously with water for several minutes. Remove    
    contact lenses, if present and easy to do. Continue rinsing.
    P312        Call a POISON CENTER or doctor/ physician if you feel unwell.    
    Supplemental Hazard        none    
    Statements
  Other hazards - none

SECTION 3: Composition/information on ingredients
  Substances
    Chemical characterization : Natural product
    Formula        : C3H4Cl2    
    Molecular Weight        : 110,97 g/mol    
    CAS-No.        : 10061-02-6    
  Hazardous ingredients according to Regulation (EC) No 1272/2008
    Component        Classification        Concentration    
  (E)-1,3-Dichloropropene
    CAS-No.        10061-02-6        Flam. Liq. 3; Eye Irrit. 2; STOT <= 100 %    
    SE 3; Skin Irrit. 2; Skin Sens.
    1; Aquatic Acute 1; Aquatic
    Chronic 1; Acute Tox. 3; Acute
    Tox. 4; Asp. Tox. 1; H226,
    H301, H304, H311, H315,
    H317, H319, H332, H335,
    H410
  Hazardous ingredients according to Directive 1999/45/EC
    Component        Classification        Concentration    
  (E)-1,3-Dichloropropene
    CAS-No.        10061-02-6        T, N, R10 - R20 - R24/25 -        <= 100 %    
    R36/37/38 - R43 - R65 -
    R50/53
    For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

SECTION 4: First aid measures
  Description of first aid measures
  General advice
    Consult a physician. Show this safety data sheet to the doctor in attendance.
  If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
  In case of skin contact
    Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
  In case of eye contact
    Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
  If swallowed
    Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
    water. Consult a physician.
  Most important symptoms and effects, both acute and delayed
    The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
    section 11
  Indication of any immediate medical attention and special treatment needed
    no data available

SECTION 5: Firefighting measures
  Extinguishing media
  Suitable extinguishing media
    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
  Special hazards arising from the substance or mixture
    Carbon oxides, Hydrogen chloride gas
  Advice for firefighters
    Wear self contained breathing apparatus for fire fighting if necessary.
  Further information
    Use water spray to cool unopened containers.

SECTION 6: Accidental release measures
  Personal precautions, protective equipment and emergency procedures
    Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove
    all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form
    explosive concentrations. Vapours can accumulate in low areas.
    For personal protection see section 8.
  Environmental precautions
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
    environment must be avoided.
  Methods and materials for containment and cleaning up
    Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
    place in container for disposal according to local regulations (see section 13).
  Reference to other sections
    For disposal see section 13.

SECTION 7: Handling and storage
  Precautions for safe handling
    Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
    Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
    charge.
    For precautions see section 2.2.
  Conditions for safe storage, including any incompatibilities
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
    opened must be carefully resealed and kept upright to prevent leakage.
    Recommended storage temperature: -20 °C
  Specific end use(s)
    A part from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection
  Control parameters
  Components with workplace control parameters
  Exposure controls
  Appropriate engineering controls
    Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
    the product.
  Personal protective equipment
  Eye/face protection
    Face shield and safety glasses Use equipment for eye protection tested and approved under
    appropriate government standards such as NIOSH (US) or EN 166(EU).
  Skin protection
    Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
    (without touching glove's outer surface) to avoid skin contact with this product. Dispose of
    contaminated gloves after use in accordance with applicable laws and good laboratory practices.
    Wash and dry hands.
    The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
    the standard EN 374 derived from it.
    Splash contact
    Material: Fluorinated rubber
    Minimum layer thickness: 0,7 mm
    Break through time: 120 min
    Material tested:Vitoject® (KCL 890 / Z677698, Size M)
    data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300,     test method: EN374
    If used in solution, or mixed with other substances, and under conditions which differ from EN 374,
    contact the supplier of the CE approved gloves. This recommendation is advisory only and must
    be evaluated by an industrial hygienist and safety officer familiar with the specific situation of
    anticipated use by our customers. It should not be construed as offering an approval for any
    specific use scenario.
  Body Protection
    Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type
    of protective equipment must be selected according to the concentration and amount of the
    dangerous substance at the specific workplace.
  Respiratory protection
    Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
    with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
    to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
    respirator. Use respirators and components tested and approved under appropriate government
    standards such as NIOSH (US) or CEN (EU).
  Control of environmental exposure
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
    the environment must be avoided.

SECTION 9: Physical and chemical properties
  Information on basic physical and chemical properties
    a) Appearance        Form: liquid    
    b) Odour        no data available    
    c) Odour Threshold        no data available    
    d) pH        no data available    
    e) Melting point/freezing        no data available    
    point
    f) Initial boiling point and 112,0 °C
    boiling range
    g) Flash point        27 °C - closed cup    
    h) Evapouration rate        no data available    
    i) Flammability (solid, gas) no data available
    j) Upper/lower        no data available    
    flammability or
    explosive limits
    k) Vapour pressure        no data available    
    l) Vapour density        no data available    
    m) Relative density        1,23 g/cm3 at 20 °C    
    n) Water solubility        no data available    
    o) Partition coefficient: n- no data available
    octanol/water
    p) Auto-ignition        no data available    
    temperature
    q) Decomposition        no data available    
    temperature
    r) Viscosity        no data available    
    s) Explosive properties        no data available    
    t) Oxidizing properties        no data available    
  Other safety information
    no data available

SECTION 10: Stability and reactivity
  Reactivity
    no data available
  Chemical stability
    Stable under recommended storage conditions.
  Possibility of hazardous reactions
    no data available
  Conditions to avoid
    Heat, flames and sparks.
  Incompatible materials
    Aluminum, Strong oxidizing agents, Metals, Halogens
  Hazardous decomposition products
    Other decomposition products - no data available
    In the event of fire: see section 5

SECTION 11: Toxicological information
  Information on toxicological effects
  Acute toxicity
    no data available
  Skin corrosion/irritation
    no data available
  Serious eye damage/eye irritation
    no data available
  Respiratory or skin sensitisation
  Germ cell mutagenicity
    no data available
  Carcinogenicity
    This product is or contains a component that has been reported to be possibly carcinogenic based on its
    IARC, ACGIH, NTP, or EPA classification.
    Limited evidence of carcinogenicity in animal studies
    IARC:        No component of this product present at levels greater than or equal to 0.1% is identified as    
    probable, possible or confirmed human carcinogen by IARC.
  Reproductive toxicity
    no data available
  Specific target organ toxicity - single exposure
    May cause respiratory irritation.
  Specific target organ toxicity - repeated exposure
    no data available
  Aspiration hazard
    May be fatal if swallowed and enters airways.
  Additional Information
    RTECS: UC8320000
    To the best of our knowledge, the chemical, physical, and toxicological properties have not been
    thoroughly investigated.
    Kidney -

SECTION 12: Ecological information
  Toxicity
    no data available
  Persistence and degradability
    no data available
  Bioaccumulative potential
    no data available
  Mobility in soil
    no data available
  Results of PBT and vPvB assessment
    PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
  Other adverse effects
    Very toxic to aquatic life with long lasting effects.

SECTION 13: Disposal considerations
  Waste treatment methods
  Product
    Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
    as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
    company.
  Contaminated packaging
    Dispose of as unused product.

SECTION 14: Transport information
  UN number
    ADR/RID: 2047        IMDG: 2047        IATA: 2047    
  UN proper shipping name
    ADR/RID: DICHLOROPROPENES
    IMDG: DICHLOROPROPENES
    IATA:        Dichloropropenes    
  Transport hazard class(es)
    ADR/RID: 3        IMDG: 3        IATA: 3    
  Packaging group
    ADR/RID: II        IMDG: II        IATA: II    
  Environmental hazards
    ADR/RID: yes        IMDG Marine pollutant: yes        IATA: no    
  Special precautions for user
    no data available

SECTION 15: Regulatory information
    This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
  Safety, health and environmental regulations/legislation specific for the substance or mixture
    no data available
  Chemical Safety Assessment
    For this product a chemical safety assessment was not carried out

SECTION 16: Other information
  Full text of H-Statements referred to under sections 2 and 3.
    Acute Tox.        Acute toxicity    
    Aquatic Acute        Acute aquatic toxicity    
    Aquatic Chronic        Chronic aquatic toxicity    
    Asp. Tox.        Aspiration hazard    
    Eye Irrit.        Eye irritation    
    Flam. Liq.        Flammable liquids    
    H226        Flammable liquid and vapour.    
    H301        Toxic if swallowed.    
    H304        May be fatal if swallowed and enters airways.    
    H311        Toxic in contact with skin.    
    H315        Causes skin irritation.    
    H317        May cause an allergic skin reaction.    
    H319        Causes serious eye irritation.    
    H332        Harmful if inhaled.    
    H335        May cause respiratory irritation.    
    H400        Very toxic to aquatic life.    
  Full text of R-phrases referred to under sections 2 and 3
    N        Dangerous for the environment    
    T        Toxic    
    R10        Flammable.    
    R20        Harmful by inhalation.    
    R24/25        Toxic in contact with skin and if swallowed.    
    R36/37/38        Irritating to eyes, respiratory system and skin.    
    R43        May cause sensitisation by skin contact.    
    R50/53        Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic    
    environment.
    R65        Harmful: may cause lung damage if swallowed.    
  Further information
    Copyright 2013 Co. LLC. License granted to make unlimited paper copies for internal use
    only.
    The above information is believed to be correct but does not purport to be all inclusive and shall be
    used only as a guide. The information in this document is based on the present state of our knowledge
    and is applicable to the product with regard to appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Corporation and its Affiliates shall not be held
    liable for any damage resulting from handling or from contact with the above product. See
     and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.
Spectrum
NMR Spectrum 1H NMR : parameter in CCl4
expand collapse
Toxicity
MUTATION DATA
expand collapse
Type of Test
Mutation in microorganisms
Exposure Route
Species Observed
Dose/Duration
20 ug/plate
Toxic Effects
--
Reference
Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 37,1915,1977
MUTATION DATA
expand collapse
Type of Test
Unscheduled DNA synthesis
Exposure Route
Species Observed
Dose/Duration
100 umol/L
Toxic Effects
--
Reference
Cancer Letters (Shannon, Ireland). (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1975- Volume(issue)/page/year: 20,263,1983
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