Butane

CAS No. 106-97-8

Formula: C4H10
Basic Info

Butane is an organic compound with the formula C4H10 that is an alkane with four carbon atoms. Butane is a gas at room temperature and atmospheric pressure. The term may refer to either of two structural isomers, n-butane or isobutane (or "methylpropane"), or to a mixture of these isomers. In the IUPAC nomenclature, however, "butane" refers only to the n-butane isomer (which is the isomer with the unbranched structure). Butanes are highly flammable, colorless, easily liquefied gases. The name butane comes from the roots but- (from butyric acid) and -ane.

Formula
C4H10
Molecular Weight
58.1222
Exact Mass
58.0783
LogP
1.8064
PSA
0
Synonyms

n-Butane

expand collapse

Properties
Appearance & Physical State
colourless gas
Density
0.579 g/mL at 20 °C(lit.)
Boiling Point
-0.5ºC
Melting Point
-138.35ºC
Flash Point
-60 °C
Refractive Index
1.3326
Stability
Stable. Extremely flammable. Readily forms explosive mixtures with air. Note low flash point. Incompatible with strong oxidizing agents, strong acids, strong alkalies.
Vapor Density
2.11 (vs air)
Vapor Pressure
1920mmHg at 25°C
Safety Info
RTECS
EJ4200000
Safety Statements
S; S9; S16
WGK Germany
-
Risk Statements
R12
HS Code
3606100000
RIDADR
UN 2037 2.1
Hazard Class
2.1
Caution Statement
P210; P377; P403; P410
Hazard Codes
Hazard Declaration
Caution Statement
MSDS
SDS 1.0
expand collapse
Download/Modify | Technical supported by XiXisys.com. For US version, EU version (23 languages) and more, please refer to xixisys.com/en/sds/search

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name butane

1.2 Other means of identification

Product number -
Other names Butane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives
Uses advised against no data available

1.4 Supplier's details

Company MOLBASE (Shanghai) Biotechnology Co., Ltd.
Address Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road,
Xuhui District, Shanghai, China
Telephone +86(21)64956998
Fax +86(21)54365166

1.5 Emergency phone number

Emergency phone number +86-400-6021-666
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

no data available

2.2 GHS label elements, including precautionary statements

Pictogram(s) no data available
Signal word

no data available

Hazard statement(s)

no data available

Precautionary statement(s)
Prevention

no data available

Response

no data available

Storage

no data available

Disposal

no data available

2.3 Other hazards which do not result in classification

no data available

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
butane butane 106-97-8 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.

In case of skin contact

ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention .

In case of eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms/effects, acute and delayed

High exposure produces drowsiness but no other evidence of systemic effect. (USCG, 1999)

4.3 Indication of immediate medical attention and special treatment needed, if necessary

FIRST AID: Skin--ON CONTACT WITH LIQUID FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention; Eyes--ON CONTACT WITH LIQUID FROSTBITE. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Specific hazards arising from the chemical

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]: EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Vapors from liquefied gas are initially heavier than air and spread along ground. CAUTION: Hydrogen (UN1049), Deuterium (UN1957), Hydrogen, refrigerated liquid (UN1966) and Methane (UN1971) are lighter than air and will rise. Hydrogen and Deuterium fires are difficult to detect since they burn with an invisible flame. Use an alternate method of detection (thermal camera, broom handle, etc.) Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket. (ERG, 2016)

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Evacuate danger area! Consult an expert! Personal protection: self-contained breathing apparatus. Ventilation. Remove all ignition sources. NEVER direct water jet on liquid.

6.3 Methods and materials for containment and cleaning up

Evacuate danger area! Consult an expert! Personal protection: self-contained breathing apparatus. Ventilation. Remove all ignition sources. NEVER direct water jet on liquid.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Fireproof. Cool.Butane in liquid form may be stored both above and below ground. Besides storage in liquefied form under its vapor pressure at normal atmospheric temperatures, refrigerated liquid storage at atmospheric pressure may be used. Such systems are closed and insulated, and the liquid petroleum gas vapor is circulated through pumps and compressors to serve as the refrigerant for the system. Butane may be stored in pits in the earth capped by metal domes and in underground chambers.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

Recommended Exposure Limit: 10 Hour Time-Weighted Average: 800 ppm (1900 mg/cu m).

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state colourless gas
Colour Colorless gas [Note: Shipped as a liquefied compressed gas. A liquid below 31 degrees F]
Odour Faint, disagreeable odor
Melting point/ freezing point -138.35ºC
Boiling point or initial boiling point and boiling range ?0.5°C(lit.)
Flammability Flammable GasExtremely flammable.
Lower and upper explosion limit / flammability limit Lower flammable limit: 1.9% by volume; Upper flammable limit: 8.5% by volume.
Flash point 45
Auto-ignition temperature 287.78°C (USCG, 1999)
Decomposition temperature no data available
pH no data available
Kinematic viscosity 7.5 at 300 K; 9.9 at 400 K; 12.2 at 500 K; 14.5 at 600 K (all in uPa.s) (gas)
Solubility 61 mg/L at 20°C
Partition coefficient n-octanol/water (log value) log Kow = 2.89
Vapour pressure 1920mmHg at 25°C
Density and/or relative density 0.579g/mLat 20°C(lit.)
Relative vapour density 2.11 (vs air)
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Highly flammable, dangerous fire ... risk.The gas is heavier than air and may travel along the ground; distant ignition possible. The gas is heavier than air and may accumulate in lowered spaces causing a deficiency of oxygen. As a result of flow, agitation, etc., electrostatic charges can be generated.BUTANE can explode when exposed to flame or when mixed with (nickel carbonyl + oxygen). It can also react with oxidizers. Strong acids and alkalis should be avoided. .

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

Very dangerous fire hazard when exposed to ... oxidizers.

10.6 Hazardous decomposition products

When heated to decomposition it emits acrid smoke and fumes.

11.Toxicological information

Acute toxicity

  • Oral: no data available
  • Inhalation: LC50 Rat inhalation 658 mg/l/4 hr
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: no data available
  • Toxicity to daphnia and other aquatic invertebrates: no data available
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

AEROBIC: A mean half-life of 5.9 days was reported for all detectable hydrocarbons in an aerobic biodegradation study of gasoline in water from a domestic sewage treatment plant(1). Among the last compounds to be degraded was butane, for which a degradation half-life was calculated as 15 days(1). Within 24 hrs, n-butane was oxidized to its corresponding methyl ketone, 2-butanone(2,3), and the corresponding alcohol, 2-butanol(3,4), by cell suspensions of over 20 methyltrophic organisms isolated from lake water and soil samples(1-3). After 192 hrs, the concentration of n-butane contained in gasoline was reduced from 0.63 to 0.37 uL/L for both a sterile control and a mixed culture sample collected from ground water contaminated with gasoline; these data indicate that n-butane was not biodegraded over the study period(5). The biodegradation of n-butane in a Columbia River soil was measured over 50 days; a degradation rate of 1.8 mgC/day/kg dry soil was reported without the addition of nitrogen(6). When nitrogen at 0.15 mg per bottle was added, the degradation rate increased to 11.4 mg C/day/kg dry soil(6). 100% of the initially added n-butane (32.9 mg/L) was biodegraded over 34 days in a screening study using an activated sludge inoculum(7).

12.3 Bioaccumulative potential

An estimated BCF of 33 was calculated for n-butane(SRC), using a log Kow of 2.89(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is moderate(SRC).

12.4 Mobility in soil

The Koc of n-butane is estimated as 900(SRC), using a measured log Kow of 2.89(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that n-butane is expected to have low mobility in soil.

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN1011 IMDG: UN1011 IATA: UN1011

14.2 UN Proper Shipping Name

ADR/RID: BUTANE
IMDG: BUTANE
IATA: BUTANE

14.3 Transport hazard class(es)

ADR/RID: 2.1 IMDG: 2.1 IATA: 2.1

14.4 Packing group, if applicable

ADR/RID: unknown IMDG: unknown IATA: unknown

14.5 Environmental hazards

ADR/RID: no IMDG: no IATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
butane butane 106-97-8 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
EC Inventory Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
Vietnam National Chemical Inventory Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 12, 2017
Revision Date Aug 12, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
MSDS
expand collapse
Name: Butane in Aerosol Container Material Safety Data Sheet
Synonym: Methylethylmethane; n-Butane; aliphatic hydrocarbon gas
CAS: 106-97-8
Section 1 - Chemical Product   MSDS Name:Butane in Aerosol Container Material Safety Data Sheet
Synonym:Methylethylmethane; n-Butane; aliphatic hydrocarbon gas

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
106-97-8 Butane 100 203-448-7
Hazard Symbols: F+
Risk Phrases: 12

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Extremely flammable.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause frostbite. May lead to the formation of blisters.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause cardiac sensitization and possible failure. May cause nausea, dizziness, and headache.
Chronic:
Chronic inhalation may cause effects similar to those of acute inhalation.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable Gas. Can form explosive mixtures at or above the flashpoint. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Will be easily ignited by heat, sparks or flame. Containers may explode when heated.
Will form explosive mixtures with air.
Extinguishing Media:
For large fires, use water spray or fog. Cool containers with flooding quantities of water until well after fire is out. For small fires, use dry chemical or carbon dioxide. Do not extinguish a leaking gas fire unless leak can be stopped.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Remove all sources of ignition. Isolate area and deny entry. Use water spray to reduce vapors, do not put water directly on leak, spill area or inside container. Prevent spreading of vapors through sewers, ventilation systems and confined areas. Stop leak only if you can do so without risk.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Prevent build up of vapors to explosive concentration. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 106-97-8: United Kingdom, WEL - TWA: 600 ppm TWA; 1450 mg/m3 TWA United Kingdom, WEL - STEL: 750 ppm STEL; 1810 mg/m3 STEL Belgium - TWA: 800 ppm VLE; 1928 mg/m3 VLE France - VME: 800 ppm VME; 1900 mg/m3 VME Germany: 1000 ppm TWA; 2400 mg/m3 TWA Japan: 500 ppm OEL; 1200 mg/m3 OEL Malaysia: 800 ppm TWA; 1900 mg/m3 TWA Netherlands: 600 ppm MAC; 1430 mg/m3 MAC Russia: 300 mg/m3 TWA Spain: 1000 ppm VLA-ED (listed under Aliphatic hydrocarbon gases mixtures alkanes C Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Aerosol
Color: colorless
Odor: faint, disagreeable
pH: Not available.
Vapor Pressure: 1557 mm Hg @20C
Viscosity: Not available.
Boiling Point: 30 deg F
Freezing/Melting Point: -216 deg F
Autoignition Temperature: 549 deg F ( 287.22 deg C)
Flash Point: -76 deg F ( -60.00 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 0.5788
Molecular Formula: C4H8
Molecular Weight: 56.056

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, nickel carbonyl, chlorine, fluorine.
Hazardous Decomposition Products:
Oxides of carbon.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 106-97-8: EJ4200000 LD50/LC50:
CAS# 106-97-8: Inhalation, mouse: LC50 = 680000 mg/m3/2H; Inhalation, rat: LC50 = 658000 mg/m3/4H.
Carcinogenicity:
Butane - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: AEROSOLS (Contains Butane)
Hazard Class: 2.1
UN Number: 1950
Packing Group:
IMO
Shipping Name: AEROSOLS (CONTAINS BUTANE)
Hazard Class: 2.1
UN Number: 1950
Packing Group:
RID/ADR
Shipping Name: AEROSOLS (Contains Butane)
Hazard Class: 2,
UN Number: 1950
Packing group:

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F+
Risk Phrases:
R 12 Extremely flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 106-97-8: 0
Canada
CAS# 106-97-8 is listed on Canada's DSL List.
CAS# 106-97-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-97-8 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Spectrum
NMR Spectrum 1H NMR : Predict
expand collapse
Home > Encyclopedia > Butane

Related Compound Information

PRODUCTS
Coming Soon
SUPPLIERS
Coming Soon
BRANDING
Coming Soon